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Here, HCHO was detected and quantified during the MTH process over HSAPO\u201034 and HZSM\u20105 by in situ synchrotron radiation photoionization mass spectrometry. Compared with conventional methods, excellent time\u2010resolved profiles were obtained to study the formation and fate of HCHO, and other products during the induction, steady\u2010state reaction, and deactivation periods. Similar formation trends of HCHO and methane, and their close correlation in yields suggest that they are derived from disproportionation of methanol at acidic sites. In the presence of Y\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    , the amount of HCHO changes, affecting the hydrogen\u2010transfer processes of olefins into aromatics and aromatics into cokes. The yield of HCHO affects the aromatic\u2010based cycle and the formation of ethylene, indicating that ethylene is mainly formed from the aromatic\u2010based cycle.\n                  <\/jats:p>","DOI":"10.1002\/anie.201914953","type":"journal-article","created":{"date-parts":[[2020,1,14]],"date-time":"2020-01-14T22:09:13Z","timestamp":1579039753000},"page":"4873-4878","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":90,"title":["Formation and Fate of Formaldehyde in Methanol\u2010to\u2010Hydrocarbon Reaction: In Situ Synchrotron Radiation Photoionization Mass Spectrometry Study"],"prefix":"10.1002","volume":"59","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8162-6504","authenticated-orcid":false,"given":"Wu","family":"Wen","sequence":"first","affiliation":[{"name":"National Synchrotron Radiation Laboratory University of Science and Technology of China  Hefei Anhui 230029 P. R. 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