{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,4]],"date-time":"2026-11-04T06:24:17Z","timestamp":1793773457518,"version":"4.6.1"},"reference-count":57,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2020,2,12]],"date-time":"2020-02-12T00:00:00Z","timestamp":1581465600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100014219","name":"National Science Fund for Distinguished Young Scholars","doi-asserted-by":"publisher","award":["21825106"],"award-info":[{"award-number":["21825106"]}],"id":[{"id":"10.13039\/501100014219","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21671175"],"award-info":[{"award-number":["21671175"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21501150"],"award-info":[{"award-number":["21501150"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U1904172"],"award-info":[{"award-number":["U1904172"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2020,3,23]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    A pair of propeller\u2010like chiral trinuclear Cu\n                    <jats:sup>I<\/jats:sup>\n                    clusters (\n                    <jats:bold>R\/S\u2010Cu3<\/jats:bold>\n                    ) with unique photoinduced fluorescence enhancement were prepared.\n                    <jats:bold>R\/S\u2010Cu3<\/jats:bold>\n                    showed intense variable luminescence after UV light irradiation, which was attributed to the stepwise oxidation of ligand in the clusters. It exhibited typical aggregation\u2010induced emission (AIE) (\n                    <jats:italic>\u03b1<\/jats:italic>\n                    <jats:sub>AIE<\/jats:sub>\n                    =17.3). Mechanism studies showed that metal cluster\u2010centered (MCC) and triplet metal\u2010to\u2010ligand charge\u2010transfer (\n                    <jats:sup>3<\/jats:sup>\n                    MLCT) processes are the origin of the luminescence; the processes are regulated by a restriction of intramolecular motions mechanism in a different state. The chiral structure and AIE feature endow\n                    <jats:bold>R\/S\u2010Cu3<\/jats:bold>\n                    with remarkable circularly polarized luminescence (\n                    <jats:italic>g<\/jats:italic>\n                    <jats:sub>lum<\/jats:sub>\n                    =2\u00d710\n                    <jats:sup>\u22122<\/jats:sup>\n                    ) in the aggregated state. It shows good capability for producing reactive oxygen species. This work enriches the kinds of atomically precise AIE clusters, gains insight into their luminescence mechanism, and offers the prospect of application in multifunctional materials.\n                  <\/jats:p>","DOI":"10.1002\/anie.201915844","type":"journal-article","created":{"date-parts":[[2020,1,20]],"date-time":"2020-01-20T13:05:10Z","timestamp":1579525510000},"page":"5336-5340","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":216,"title":["Photoresponsive Propeller\u2010like Chiral AIE Copper(I) Clusters"],"prefix":"10.1002","volume":"59","author":[{"given":"Yu\u2010Jin","family":"Kong","sequence":"first","affiliation":[{"name":"Green Catalysis Center College of Chemistry Zhengzhou University  Zhengzhou 450001 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhi\u2010Ping","family":"Yan","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210023 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Si","family":"Li","sequence":"additional","affiliation":[{"name":"Green Catalysis Center College of Chemistry Zhengzhou University  Zhengzhou 450001 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui\u2010Fang","family":"Su","sequence":"additional","affiliation":[{"name":"Green Catalysis Center College of Chemistry Zhengzhou University  Zhengzhou 450001 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9458-4796","authenticated-orcid":false,"given":"Kai","family":"Li","sequence":"additional","affiliation":[{"name":"Green Catalysis Center College of Chemistry Zhengzhou University  Zhengzhou 450001 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"You\u2010Xuan","family":"Zheng","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210023 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6728-0559","authenticated-orcid":false,"given":"Shuang\u2010Quan","family":"Zang","sequence":"additional","affiliation":[{"name":"Green Catalysis Center College of Chemistry Zhengzhou University  Zhengzhou 450001 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,2,12]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00060"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00444G"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201802060"},{"key":"e_1_2_2_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201802060"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201900366"},{"key":"e_1_2_2_5_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201900366"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b00636"},{"key":"e_1_2_2_7_1","unstructured":"\u00a0"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/b105159h"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1cs15113d"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00325J"},{"key":"e_1_2_2_11_1","unstructured":"\u00a0"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2718"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b00773"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201709827"},{"key":"e_1_2_2_14_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201709827"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201802932"},{"key":"e_1_2_2_15_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201802932"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00800K"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b01283"},{"key":"e_1_2_2_18_2","author":"Zhang M. M.","year":"2019","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_2_18_3","unstructured":"Angew. Chem. 2019"},{"key":"e_1_2_2_19_1","unstructured":"\u00a0"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja508962m"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00044G"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4SC03365E"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5SC01946J"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7SC03076B"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b07738"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8QM00096D"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-05476-y"},{"key":"e_1_2_2_28_1","unstructured":"\u00a0"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39890000714"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00074"},{"key":"e_1_2_2_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja306199p"},{"key":"e_1_2_2_32_1","unstructured":"\u00a0"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201401356"},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00263"},{"key":"e_1_2_2_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/0010-8545(90)80078-8"},{"key":"e_1_2_2_36_1","unstructured":"\u00a0"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b03844"},{"key":"e_1_2_2_38_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201906614"},{"key":"e_1_2_2_38_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201906614"},{"key":"e_1_2_2_39_1","unstructured":"\u00a0"},{"key":"e_1_2_2_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/advs.201801304"},{"key":"e_1_2_2_41_2","doi-asserted-by":"crossref","first-page":"2750","DOI":"10.1002\/chem.201805381","volume":"25","author":"Wei Z.","year":"2018","journal-title":"Chem. Eur. J."},{"key":"e_1_2_2_42_1","unstructured":"\u00a0"},{"key":"e_1_2_2_43_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01581a057"},{"key":"e_1_2_2_44_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00882a030"},{"key":"e_1_2_2_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00231a005"},{"key":"e_1_2_2_46_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00017a044"},{"key":"e_1_2_2_47_1","unstructured":"\u00a0"},{"key":"e_1_2_2_48_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201801350"},{"key":"e_1_2_2_49_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2018.06.003"},{"key":"e_1_2_2_50_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9QM00242A"},{"key":"e_1_2_2_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.biomaterials.2019.119330"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201915844","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201915844","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.201915844","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201915844","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,7]],"date-time":"2023-09-07T11:30:09Z","timestamp":1694086209000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201915844"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,2,12]]},"references-count":57,"journal-issue":{"issue":"13","published-print":{"date-parts":[[2020,3,23]]}},"alternative-id":["10.1002\/anie.201915844"],"URL":"https:\/\/doi.org\/10.1002\/anie.201915844","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,2,12]]},"assertion":[{"value":"2019-12-11","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-02-12","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}