{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,22]],"date-time":"2026-04-22T13:43:28Z","timestamp":1776865408320,"version":"3.51.2"},"reference-count":53,"publisher":"Wiley","issue":"14","license":[{"start":{"date-parts":[[2020,1,24]],"date-time":"2020-01-24T00:00:00Z","timestamp":1579824000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2020,3,27]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The oxidation of Fe(CO)<jats:sub>5<\/jats:sub> with the [NO]<jats:sup>+<\/jats:sup> salt of the weakly coordinating perfluoroalkoxyaluminate anion [F\u2010{Al(OR<jats:sup>F<\/jats:sup>)<jats:sub>3<\/jats:sub>}<jats:sub>2<\/jats:sub>]<jats:sup>\u2212<\/jats:sup> (R<jats:sup>F<\/jats:sup>=C(CF<jats:sub>3<\/jats:sub>)<jats:sub>3<\/jats:sub>) leads to stable salts of the 18\u2005valence electron (VE) species [Fe(CO)<jats:sub>4<\/jats:sub>(NO)]<jats:sup>+<\/jats:sup> and [Fe(CO)(NO)<jats:sub>3<\/jats:sub>]<jats:sup>+<\/jats:sup> with the Enemark\u2013Feltham numbers of {FeNO}<jats:sup>8<\/jats:sup> and {FeNO}<jats:sup>10<\/jats:sup>. This finally concludes the triad of heteroleptic iron carbonyl\/nitrosyl complexes, since the first discovery of the anionic ([Fe(CO)<jats:sub>3<\/jats:sub>(NO)]<jats:sup>\u2212<\/jats:sup>) and neutral ([Fe(CO)<jats:sub>2<\/jats:sub>(NO)<jats:sub>2<\/jats:sub>]) species over 80\u2005years ago. Both complexes were fully characterized (IR, Raman, NMR, UV\/Vis, scXRD, pXRD) and are stable at room temperature under inert conditions over months and may serve as useful starting materials for further investigations.<\/jats:p>","DOI":"10.1002\/anie.201915942","type":"journal-article","created":{"date-parts":[[2019,12,17]],"date-time":"2019-12-17T18:17:16Z","timestamp":1576606636000},"page":"5581-5585","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["Stable Salts of Heteroleptic Iron Carbonyl\/Nitrosyl Cations"],"prefix":"10.1002","volume":"59","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8421-2067","authenticated-orcid":false,"given":"Jan","family":"Bohnenberger","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Anorganische und Analytische Chemie and Freiburger Materialforschungszentrum (FMF) Universit\u00e4t Freiburg  Albertstrasse 21 79104 Freiburg 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