{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,3]],"date-time":"2026-10-03T03:59:59Z","timestamp":1790999999985,"version":"4.1.0"},"reference-count":115,"publisher":"Wiley","issue":"33","license":[{"start":{"date-parts":[[2020,6,3]],"date-time":"2020-06-03T00:00:00Z","timestamp":1591142400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["NRF-2019R1C1C1006058"],"award-info":[{"award-number":["NRF-2019R1C1C1006058"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2020,8,10]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>We report the dual postsynthetic modification (PSM) of a metal\u2013organic framework (MOF) involving the microscopic conversion of C\u2212H bonds into C\u2212C bonds and the mesoscopic introduction of hierarchical porosity. MOF crystals underwent single\u2010crystal\u2010to\u2010single\u2010crystal transformations during the electrophilic aromatic substitution of Co<jats:sub>2<\/jats:sub>(<jats:italic>m<\/jats:italic>\u2010DOBDC) (<jats:italic>m<\/jats:italic>\u2010DOBDC<jats:sup>4\u2212<\/jats:sup>=4,6\u2010dioxo\u20101,3\u2010benzenedicarboxylate) with alkyl halides and formaldehyde. The steric hindrance caused by the proximity of the introduced functional groups to the coordination bonds reduced bond stability and facilitated the transformation into hierarchically porous mesostructures by etching with in situ generated protons (hydroniums) and halides. The numerous defect sites in the mesostructural MOFs are potential water\u2010sorption sites. However, since the introduced functional groups are close to the main adsorption sites, even methyl groups are able to considerably decrease water adsorption, whereas hydroxy groups increase adsorption at low vapor pressures.<\/jats:p>","DOI":"10.1002\/anie.202000278","type":"journal-article","created":{"date-parts":[[2020,4,27]],"date-time":"2020-04-27T08:13:07Z","timestamp":1587975187000},"page":"13793-13799","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":43,"title":["Microscopic and Mesoscopic Dual Postsynthetic Modifications of Metal\u2013Organic Frameworks"],"prefix":"10.1002","volume":"59","author":[{"given":"Byeongchan","family":"Lee","sequence":"first","affiliation":[{"name":"Department of Emerging Materials Science Daegu-Gyeongbuk Institute of Science and Technology (DGIST)  333 Techno Jungang-daero, Dalseong-gun Daegu 42988 Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dohyun","family":"Moon","sequence":"additional","affiliation":[{"name":"Beamline Department Pohang Accelerator Laboratory  Pohang 37673 Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7755-5889","authenticated-orcid":false,"given":"Jinhee","family":"Park","sequence":"additional","affiliation":[{"name":"Department of Emerging Materials Science Daegu-Gyeongbuk Institute of Science and Technology (DGIST)  333 Techno Jungang-daero, Dalseong-gun Daegu 42988 Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,6,3]]},"reference":[{"key":"e_1_2_6_1_1","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr300014x"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b802256a"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr2003272"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3SC52633J"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00153C"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201705189"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr200324t"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00010B"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2017.06.007"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2018.05.017"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr200256v"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00125"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2019.01.001"},{"key":"e_1_2_6_15_1","unstructured":"\u00a0"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr200179u"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00076E"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2017.11.015"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b00733"},{"key":"e_1_2_6_20_1","unstructured":"\u00a0"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja5063423"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms9348"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201611254"},{"key":"e_1_2_6_23_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201611254"},{"key":"e_1_2_6_24_1","unstructured":"\u00a0"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja074366o"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200800686"},{"key":"e_1_2_6_26_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200800686"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja7111564"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200802908"},{"key":"e_1_2_6_28_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200802908"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja7114053"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200802545"},{"key":"e_1_2_6_30_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200802545"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja907742z"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja909613e"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja3063919"},{"key":"e_1_2_6_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.9b04768"},{"key":"e_1_2_6_35_1","unstructured":"\u00a0"},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200905898"},{"key":"e_1_2_6_36_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200905898"},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201001551"},{"key":"e_1_2_6_37_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201001551"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic102436b"},{"key":"e_1_2_6_39_1","unstructured":"\u00a0"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja506230r"},{"key":"e_1_2_6_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b06397"},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8EE01332B"},{"key":"e_1_2_6_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/ijch.201800117"},{"key":"e_1_2_6_44_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja8036096"},{"key":"e_1_2_6_45_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0909718106"},{"key":"e_1_2_6_46_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b02061"},{"key":"e_1_2_6_47_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.6b08851"},{"key":"e_1_2_6_48_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201906222"},{"key":"e_1_2_6_48_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201906222"},{"key":"e_1_2_6_49_1","unstructured":"\u00a0"},{"key":"e_1_2_6_50_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja300034j"},{"key":"e_1_2_6_51_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature14327"},{"key":"e_1_2_6_52_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA02357B"},{"key":"e_1_2_6_53_1","unstructured":"\u00a0"},{"key":"e_1_2_6_54_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00715A"},{"key":"e_1_2_6_55_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00599J"},{"key":"e_1_2_6_56_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00935A"},{"key":"e_1_2_6_57_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201904969"},{"key":"e_1_2_6_58_1","unstructured":"\u00a0"},{"key":"e_1_2_6_59_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1220131"},{"key":"e_1_2_6_60_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature15734"},{"key":"e_1_2_6_61_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b04872"},{"key":"e_1_2_6_62_1","unstructured":"\u00a0"},{"key":"e_1_2_6_63_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA10416E"},{"key":"e_1_2_6_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.5b00315"},{"key":"e_1_2_6_65_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp402884h"},{"key":"e_1_2_6_66_1","unstructured":"\u00a0"},{"key":"e_1_2_6_67_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms9847"},{"key":"e_1_2_6_68_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201405752"},{"key":"e_1_2_6_69_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms15356"},{"key":"e_1_2_6_70_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201903323"},{"key":"e_1_2_6_70_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201903323"},{"key":"e_1_2_6_71_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201901744"},{"key":"e_1_2_6_72_2","author":"Feng L.","year":"2020","journal-title":"Natl. Sci. Rev."},{"key":"e_1_2_6_73_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-017-00526-3"},{"key":"e_1_2_6_74_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b03517"},{"key":"e_1_2_6_75_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms4621"},{"key":"e_1_2_6_76_1","unstructured":"\u00a0"},{"key":"e_1_2_6_77_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF01139044"},{"key":"e_1_2_6_78_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201100283"},{"key":"e_1_2_6_79_1","unstructured":"\u00a0"},{"key":"e_1_2_6_80_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.96.155207"},{"key":"e_1_2_6_81_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.100.205123"},{"key":"e_1_2_6_82_1","unstructured":"\u00a0"},{"key":"e_1_2_6_83_2","doi-asserted-by":"publisher","DOI":"10.1515\/pac-2014-1117"},{"key":"e_1_2_6_84_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS90043G"},{"key":"e_1_2_6_85_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00391E"},{"key":"e_1_2_6_86_1","unstructured":"\u00a0"},{"key":"e_1_2_6_87_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201506391"},{"key":"e_1_2_6_87_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201506391"},{"key":"e_1_2_6_88_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201507588"},{"key":"e_1_2_6_88_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201507588"},{"key":"e_1_2_6_89_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7SC02886E"},{"key":"e_1_2_6_90_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201701604"},{"key":"e_1_2_6_90_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201701604"},{"key":"e_1_2_6_91_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6SC04903F"},{"key":"e_1_2_6_92_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201705020"},{"key":"e_1_2_6_93_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201905006"},{"key":"e_1_2_6_93_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201905006"},{"key":"e_1_2_6_94_1","unstructured":"\u00a0"},{"key":"e_1_2_6_95_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr5002589"},{"key":"e_1_2_6_96_2","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201601296"},{"key":"e_1_2_6_97_2","doi-asserted-by":"publisher","DOI":"10.3390\/ma11112250"},{"key":"e_1_2_6_98_1","unstructured":"\u00a0"},{"key":"e_1_2_6_99_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201707634"},{"key":"e_1_2_6_100_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201800202"},{"key":"e_1_2_6_101_1","unstructured":"\u00a0"},{"key":"e_1_2_6_102_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja204757x"},{"key":"e_1_2_6_103_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja406081r"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.202000278","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202000278","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202000278","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202000278","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,29]],"date-time":"2023-08-29T13:48:03Z","timestamp":1693316883000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202000278"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,6,3]]},"references-count":115,"journal-issue":{"issue":"33","published-print":{"date-parts":[[2020,8,10]]}},"alternative-id":["10.1002\/anie.202000278"],"URL":"https:\/\/doi.org\/10.1002\/anie.202000278","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,6,3]]},"assertion":[{"value":"2020-01-07","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-06-03","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}