{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T18:07:42Z","timestamp":1790705262184,"version":"4.1.0"},"reference-count":79,"publisher":"Wiley","issue":"22","license":[{"start":{"date-parts":[[2020,3,24]],"date-time":"2020-03-24T00:00:00Z","timestamp":1585008000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100000002","name":"National Institutes of Health","doi-asserted-by":"publisher","award":["R01GM116987"],"award-info":[{"award-number":["R01GM116987"]}],"id":[{"id":"10.13039\/100000002","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2020,5,25]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>A catalytic diastereo\u2010 and enantioselective method for the preparation of complex tertiary homoallylic alcohols containing a vicinal quaternary carbon stereogenic center and a versatile alkenylboronic ester is disclosed. Transformations are promoted by 5\u2005mol\u2009% of a readily available copper catalyst bearing a bulky monodentate phosphoramidite ligand, which is essential for attaining both high dr and er. Reactions proceed with a wide variety of ketones and allylic 1,1\u2010diboronate reagents, which enables the efficient preparation of diverse array of molecular scaffolds.<\/jats:p>","DOI":"10.1002\/anie.202000675","type":"journal-article","created":{"date-parts":[[2020,2,26]],"date-time":"2020-02-26T14:41:53Z","timestamp":1582728113000},"page":"8451-8455","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":55,"title":["Cu\u2010Catalyzed Diastereo\u2010 and Enantioselective Reactions of \u03b3,\u03b3\u2010Disubstituted Allyldiboron Compounds with Ketones"],"prefix":"10.1002","volume":"59","author":[{"given":"Joseph M.","family":"Zanghi","sequence":"first","affiliation":[{"name":"Department of Chemistry The University of North Carolina at Chapel Hill  Chapel Hill NC 27599 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7537-9420","authenticated-orcid":false,"given":"Simon J.","family":"Meek","sequence":"additional","affiliation":[{"name":"Department of Chemistry The University of North Carolina at Chapel Hill  Chapel Hill NC 27599 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,3,24]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"Recent reviews on the enantioselective synthesis of quaternary carbon stereogenic 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