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Complex\n                    <jats:bold>2<\/jats:bold>\n                    reacts readily with PhCCH and N\n                    <jats:sub>2<\/jats:sub>\n                    O to form [K(2.2.2\u2010cryptand)][\n                    <jats:sup>Me<\/jats:sup>\n                    LZn(SH)(CCPh)] (\n                    <jats:bold>4<\/jats:bold>\n                    ) and [K(2.2.2\u2010cryptand)][\n                    <jats:sup>Me<\/jats:sup>\n                    LZn(SNNO)] (\n                    <jats:bold>5<\/jats:bold>\n                    ), respectively, displaying both Br\u00f8nsted and Lewis basicity. In addition, the electronic structure of\n                    <jats:bold>2<\/jats:bold>\n                    was examined computationally and compared with the previously reported Ni congener, [K(2.2.2\u2010cryptand)][\n                    <jats:sup>tBu<\/jats:sup>\n                    LNi(S)] (\n                    <jats:sup>tBu<\/jats:sup>\n                    L={(2,6\u2010\n                    <jats:sup>i<\/jats:sup>\n                    Pr\n                    <jats:sub>2<\/jats:sub>\n                    C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>3<\/jats:sub>\n                    )NC(\n                    <jats:sup>t<\/jats:sup>\n                    Bu)}\n                    <jats:sub>2<\/jats:sub>\n                    CH).\n                  <\/jats:p>","DOI":"10.1002\/anie.202002364","type":"journal-article","created":{"date-parts":[[2020,3,20]],"date-time":"2020-03-20T15:09:03Z","timestamp":1584716943000},"page":"8947-8951","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Synthesis of a \u201cMasked\u201d Terminal Zinc Sulfide and Its Reactivity with Br\u00f8nsted and Lewis Acids"],"prefix":"10.1002","volume":"59","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2517-4077","authenticated-orcid":false,"given":"Miguel \u00c1.","family":"Baeza Cinco","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry University of California, Santa Barbara  Santa Barbara CA 93016 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guang","family":"Wu","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry University of California, Santa Barbara  Santa Barbara CA 93016 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nikolas","family":"Kaltsoyannis","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Manchester  Oxford Road Manchester M13 9PL UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4370-1424","authenticated-orcid":false,"given":"Trevor W.","family":"Hayton","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry University of California, Santa Barbara  Santa Barbara CA 93016 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,4,15]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1193478"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr9500500"},{"key":"e_1_2_2_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja106102b"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1422800112"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500266a"},{"key":"e_1_2_2_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00664"},{"key":"e_1_2_2_7_1","first-page":"17","volume-title":"Molecular Electronic Structures of Transition Metal Complexes I","author":"Winkler J. 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