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The excellent <jats:italic>ortho<\/jats:italic>\u2010selectivity results from a four\u2010membered metallacyclic intermediate involving phosphorus chelation. The developed system can be extended to the benzylic C\u2212H silylation of arylphosphines. Diverse silylated arylphosphines are produced, exhibiting broad functional group compatibility. Further functionalization of the products under mild conditions renders the formed compounds useful building blocks.<\/jats:p>","DOI":"10.1002\/anie.202003865","type":"journal-article","created":{"date-parts":[[2020,4,3]],"date-time":"2020-04-03T15:31:06Z","timestamp":1585927866000},"page":"10909-10912","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":66,"title":["Revealing Silylation of C(sp<sup>2<\/sup>)\/C(sp<sup>3<\/sup>)\u2013H Bonds in Arylphosphines by Ruthenium Catalysis"],"prefix":"10.1002","volume":"59","author":[{"given":"Jian","family":"Wen","sequence":"first","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry Chemistry and Biomedicine Innovation Center (ChemBIC) School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ben","family":"Dong","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry Chemistry and Biomedicine Innovation Center (ChemBIC) School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinjun","family":"Zhu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry Chemistry and Biomedicine Innovation Center (ChemBIC) School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yue","family":"Zhao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry Chemistry and Biomedicine Innovation Center (ChemBIC) School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4571-4413","authenticated-orcid":false,"given":"Zhuangzhi","family":"Shi","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry Chemistry and Biomedicine Innovation Center (ChemBIC) School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,5,8]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00037a011"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr941074u"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9902805"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1359-6446(03)02726-0"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/jm3010114"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/b816769a"},{"key":"e_1_2_2_8_1","unstructured":"\u00a0"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/om051080o"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/om900874p"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201103719"},{"key":"e_1_2_2_11_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201103719"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja410822p"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/om400047j"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/om501238d"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.3519"},{"key":"e_1_2_2_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b07064"},{"key":"e_1_2_2_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2005.10.003"},{"key":"e_1_2_2_18_1","first-page":"597","volume":"5","author":"Sabo S.","year":"1981","journal-title":"Nouv. 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