{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,3]],"date-time":"2026-10-03T01:15:41Z","timestamp":1790990141349,"version":"4.1.0"},"reference-count":71,"publisher":"Wiley","issue":"33","license":[{"start":{"date-parts":[[2020,6,3]],"date-time":"2020-06-03T00:00:00Z","timestamp":1591142400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100010663","name":"H2020 European Research Council","doi-asserted-by":"publisher","award":["CoG 772299"],"award-info":[{"award-number":["CoG 772299"]}],"id":[{"id":"10.13039\/100010663","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100007215","name":"Verband der Chemischen Industrie","doi-asserted-by":"publisher","award":["Kekul\u00e9 Stipendium"],"award-info":[{"award-number":["Kekul\u00e9 Stipendium"]}],"id":[{"id":"10.13039\/100007215","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2020,8,10]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The reaction of zerovalent nickel compounds with white phosphorus (P<jats:sub>4<\/jats:sub>) is a barely explored route to binary nickel phosphide clusters. Here, we show that coordinatively and electronically unsaturated N\u2010heterocyclic carbene (NHC) nickel(0) complexes afford unusual cluster compounds with P<jats:sub>1<\/jats:sub>, P<jats:sub>3<\/jats:sub>, P<jats:sub>5<\/jats:sub> and P<jats:sub>8<\/jats:sub> units. Using [Ni(IMes)<jats:sub>2<\/jats:sub>] [IMes=1,3\u2010bis(2,4,6\u2010trimethylphenyl)imidazolin\u20102\u2010ylidene], electron\u2010deficient Ni<jats:sub>3<\/jats:sub>P<jats:sub>4<\/jats:sub> and Ni<jats:sub>3<\/jats:sub>P<jats:sub>6<\/jats:sub> clusters have been isolated, which can be described as <jats:italic>superhypercloso<\/jats:italic> and <jats:italic>hypercloso<\/jats:italic> clusters according to the Wade\u2013Mingos rules. Use of the bulkier NHC complexes [Ni(IPr)<jats:sub>2<\/jats:sub>] or [(IPr)Ni(\u03b7<jats:sup>6<\/jats:sup>\u2010toluene)] [IPr=1,3\u2010bis(2,6\u2010diisopropylphenyl)imidazolin\u20102\u2010ylidene] affords a <jats:italic>closo<\/jats:italic>\u2010Ni<jats:sub>3<\/jats:sub>P<jats:sub>8<\/jats:sub> cluster. Inverse\u2010sandwich complexes [(NHC)<jats:sub>2<\/jats:sub>Ni<jats:sub>2<\/jats:sub>P<jats:sub>5<\/jats:sub>] (NHC=IMes, IPr) with an aromatic <jats:italic>cyclo<\/jats:italic>\u2010P<jats:sub>5<\/jats:sub><jats:sup>\u2212<\/jats:sup> ligand were identified as additional products.<\/jats:p>","DOI":"10.1002\/anie.202004020","type":"journal-article","created":{"date-parts":[[2020,4,29]],"date-time":"2020-04-29T20:40:59Z","timestamp":1588192859000},"page":"14148-14153","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":26,"title":["Aggregation and Degradation of White Phosphorus Mediated by N\u2010Heterocyclic Carbene Nickel(0) Complexes"],"prefix":"10.1002","volume":"59","author":[{"given":"Gabriele","family":"Hierlmeier","sequence":"first","affiliation":[{"name":"Universit\u00e4t Regensburg Institut f\u00fcr Anorganische Chemie  93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1387-4148","authenticated-orcid":false,"given":"Peter","family":"Coburger","sequence":"additional","affiliation":[{"name":"Universit\u00e4t Regensburg Institut f\u00fcr Anorganische Chemie  93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0859-1696","authenticated-orcid":false,"given":"Nicolaas P.","family":"van Leest","sequence":"additional","affiliation":[{"name":"University of Amsterdam van 't Hoff Institute for Molecular Sciences  Science Park 904 1098 XH Amsterdam The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3482-7669","authenticated-orcid":false,"given":"Bas","family":"de Bruin","sequence":"additional","affiliation":[{"name":"University of Amsterdam van 't Hoff Institute for Molecular Sciences  Science Park 904 1098 XH Amsterdam The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4066-6483","authenticated-orcid":false,"given":"Robert","family":"Wolf","sequence":"additional","affiliation":[{"name":"Universit\u00e4t Regensburg Institut f\u00fcr Anorganische Chemie  93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,6,3]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr900349u"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr9003709"},{"key":"e_1_2_2_3_1","unstructured":"\u00a0"},{"key":"e_1_2_2_4_2","volume-title":"Phosphorus 2000. Chemistry, Biochemistry and Technology","author":"Corbridge D. E. C.","year":"2000"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201400115"},{"key":"e_1_2_2_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr00083a012"},{"key":"e_1_2_2_7_1","unstructured":"\u00a0"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00476a049"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00501a019"},{"key":"e_1_2_2_10_1","unstructured":"\u00a0"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(88)80385-1"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19901230310"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19921251207"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201601775"},{"key":"e_1_2_2_14_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201601775"},{"key":"e_1_2_2_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC02601B"},{"key":"e_1_2_2_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.197904691"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19790910621"},{"key":"e_1_2_2_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/b802454e"},{"key":"e_1_2_2_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201201368"},{"key":"e_1_2_2_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/om050078u"},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC01572G"},{"key":"e_1_2_2_21_1","unstructured":"\u00a0"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00089a029"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.7b01034"},{"key":"e_1_2_2_24_1","unstructured":"\u00a0"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b05574"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.8b00786"},{"key":"e_1_2_2_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/om500088p"},{"key":"e_1_2_2_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1sc00413a"},{"key":"e_1_2_2_29_1","unstructured":"\u00a0"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00060a059"},{"key":"e_1_2_2_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00375a019"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/om800329u"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201205943"},{"key":"e_1_2_2_33_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201205943"},{"key":"e_1_2_2_34_2","first-page":"657","author":"Henkel G.","year":"1988","journal-title":"J. Chem. Soc. Chem. Commun."},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201900302"},{"key":"e_1_2_2_36_1","unstructured":"\u00a0"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher","DOI":"10.1039\/c29710000792"},{"key":"e_1_2_2_38_2","doi-asserted-by":"publisher","DOI":"10.1038\/physci236099a0"},{"key":"e_1_2_2_39_1","unstructured":"\u00a0"},{"key":"e_1_2_2_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.19960020217"},{"key":"e_1_2_2_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19966220908"},{"key":"e_1_2_2_42_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.19970030917"},{"key":"e_1_2_2_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3749(199803)624:3<367::AID-ZAAC367>3.0.CO;2-R"},{"key":"e_1_2_2_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201101038"},{"key":"e_1_2_2_44_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201101038"},{"key":"e_1_2_2_45_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC09730A"},{"key":"e_1_2_2_46_1","unstructured":"\u00a0"},{"key":"e_1_2_2_47_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0682(200211)2002:11<3018::AID-EJIC3018>3.0.CO;2-A"},{"key":"e_1_2_2_48_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19891221104"},{"key":"e_1_2_2_49_1","unstructured":"\u00a0"},{"key":"e_1_2_2_50_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19921250506"},{"key":"e_1_2_2_51_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT01750E"},{"key":"e_1_2_2_52_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201203980"},{"key":"e_1_2_2_52_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201203980"},{"key":"e_1_2_2_53_2","doi-asserted-by":"publisher","DOI":"10.1039\/DT9900000977"},{"key":"e_1_2_2_54_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2018.06.025"},{"key":"e_1_2_2_55_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198603631"},{"key":"e_1_2_2_55_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19860980416"},{"key":"e_1_2_2_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3749(199907)625:7<1193::AID-ZAAC1193>3.0.CO;2-L"},{"key":"e_1_2_2_57_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0567740869001853"},{"key":"e_1_2_2_58_1","unstructured":"Heating up the solution of4in [D8]toluene to temperatures above 313\u2005K led to decomposition to unidentified products."},{"key":"e_1_2_2_59_1","unstructured":"\u00a0"},{"key":"e_1_2_2_60_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1626543"},{"key":"e_1_2_2_61_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1696113"},{"key":"e_1_2_2_62_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(02)01031-9"},{"key":"e_1_2_2_63_1","unstructured":"\u00a0"},{"key":"e_1_2_2_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja403440e"},{"key":"e_1_2_2_65_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201801964"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.202004020","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202004020","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202004020","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202004020","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,29]],"date-time":"2023-08-29T13:50:58Z","timestamp":1693317058000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202004020"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,6,3]]},"references-count":71,"journal-issue":{"issue":"33","published-print":{"date-parts":[[2020,8,10]]}},"alternative-id":["10.1002\/anie.202004020"],"URL":"https:\/\/doi.org\/10.1002\/anie.202004020","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,6,3]]},"assertion":[{"value":"2020-03-18","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-06-03","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}