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Its metal\u2010deficient core contains the lowest possible number of Cu atoms to connect 12 pentaphosphaferrocene units, providing a supramolecule with fullerene topology which, topologically, also represents the simplest homologue in the family of metal\u2010deficient pentaphosphaferrocene\u2010based supramolecules [{Cp<jats:sup>R<\/jats:sup>Fe(\u03b7<jats:sup>5<\/jats:sup>\u2010P<jats:sub>5<\/jats:sub>)}<jats:sub>12<\/jats:sub>(CuX)<jats:sub>20\u2212<jats:italic>n<\/jats:italic><\/jats:sub>]. The 12 vacant metal sites between the cyclo\u2010P<jats:sub>5<\/jats:sub> rings, the largest number attained to date, make this compound a facile precursor for potential inner and outer modifications of the core as well as for functionalization via the substitution of labile acetonitrile ligands.<\/jats:p>","DOI":"10.1002\/anie.202004988","type":"journal-article","created":{"date-parts":[[2020,4,24]],"date-time":"2020-04-24T15:02:15Z","timestamp":1587740535000},"page":"13647-13650","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Metal\u2010Deficient Supramolecule Based on a Fivefold\u2010Symmetric Building Block"],"prefix":"10.1002","volume":"59","author":[{"given":"Jana","family":"Schiller","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry, Dept. of Chemistry and Pharmacy University of Regensburg  Universit\u00e4tsstr. 31 93053 Regensburg 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