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The N\u2013N linkage in the skeleton of <jats:bold>Cu\u20105<\/jats:bold>, which serves as a mediator of \u03c0\u2010electron delocalization, features an 18\u03c0 aromatic system. The electronic structure of <jats:bold>Cu\u20105<\/jats:bold> is best described as a ground\u2010state singlet species stabilized by the distinct NNCC coordination core. This finding shows how the ligand's design can be used to modulate the Cu <jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/anie202005167-math-0001.png\" xlink:title=\"urn:x-wiley:14337851:media:anie202005167:anie202005167-math-0001\"\/>\n orbital energy, thereby making such compounds invaluable for copper\u2010based catalytic applications.<\/jats:p>","DOI":"10.1002\/anie.202005167","type":"journal-article","created":{"date-parts":[[2020,5,25]],"date-time":"2020-05-25T14:31:07Z","timestamp":1590417067000},"page":"15897-15901","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":25,"title":["Copper 1,19\u2010Diaza\u201021,24\u2010dicarbacorrole: A Corrole Analogue with an N\u2212N Linkage Stabilizes a Ground\u2010State Singlet Organocopper 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