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There have been numerous reports of the H\u2010S system over the last five years, but important questions remain unanswered. It is crucial to verify whether the T<jats:sub>c<\/jats:sub> was determined correctly for samples prepared from compressed H<jats:sub>2<\/jats:sub>S, since they are inevitably contaminated with H\u2010depleted byproducts. Here, we prepare stoichiometric H<jats:sub>3<\/jats:sub>S by direct in\u2005situ synthesis from elemental S and excess H<jats:sub>2<\/jats:sub>. The Im<jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/anie202007091-math-0001.png\" xlink:title=\"urn:x-wiley:14337851:media:anie202007091:anie202007091-math-0001\"\/>\nm phase of D<jats:sub>3<\/jats:sub>S samples exhibits a T<jats:sub>c<\/jats:sub> significantly higher than previously reported values (ca. 150\u2005K), reaching a maximum T<jats:sub>c<\/jats:sub> of 166\u2005K at 157\u2005GPa. Furthermore, we confirm that the sharp decrease in T<jats:sub>c<\/jats:sub> below 150\u2005GPa is accompanied by continuous rhombohedral structural distortions and demonstrate that the Cccm phase is non\u2010metallic, with molecular H<jats:sub>2<\/jats:sub> units in the crystal structure.<\/jats:p>","DOI":"10.1002\/anie.202007091","type":"journal-article","created":{"date-parts":[[2020,7,7]],"date-time":"2020-07-07T01:45:58Z","timestamp":1594086358000},"page":"18970-18974","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":44,"title":["A Boosted Critical Temperature of 166\u2005K in Superconducting D<sub>3<\/sub>S Synthesized from Elemental Sulfur and Hydrogen"],"prefix":"10.1002","volume":"59","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8134-8380","authenticated-orcid":false,"given":"Vasily S.","family":"Minkov","sequence":"first","affiliation":[{"name":"Max-Planck Institut f\u00fcr Chemie  Hahn-Meitner Weg 1 55128 Mainz Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9270-2330","authenticated-orcid":false,"given":"Vitali B.","family":"Prakapenka","sequence":"additional","affiliation":[{"name":"Center for Advanced Radiation Sources University of Chicago  5640 South Ellis Avenue 60637 Chicago IL USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1630-0628","authenticated-orcid":false,"given":"Eran","family":"Greenberg","sequence":"additional","affiliation":[{"name":"Applied Physics Department Soreq Nuclear Research Center  81800 Yavne Israel"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9861-3152","authenticated-orcid":false,"given":"Mikhail I.","family":"Eremets","sequence":"additional","affiliation":[{"name":"Max-Planck Institut f\u00fcr Chemie  Hahn-Meitner Weg 1 55128 Mainz Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,8,26]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRev.108.1175"},{"key":"e_1_2_2_2_1","unstructured":"\u00a0"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1749590"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.21.1748"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF01007238"},{"key":"e_1_2_2_6_1","unstructured":"\u00a0"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aal1579"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41567-019-0646-x"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-019-1927-3"},{"key":"e_1_2_2_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/nphys625"},{"key":"e_1_2_2_11_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.92.187002"},{"key":"e_1_2_2_12_1","unstructured":"\u00a0"},{"key":"e_1_2_2_13_2","unstructured":"A.\u2005P. 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