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Despite their high ionic conductivity and desirable mechanical properties, many known sulfide solid electrolytes exhibit poor air stability. The spontaneous hydrolysis reactions of sulfides with moisture in air lead to the release of toxic hydrogen sulfide and materials degradation, hindering large\u2010scale manufacturing and applications of sulfide\u2010based solid\u2010state batteries. In this work, we systematically investigate the hydrolysis and reduction reactions in Li\u2010 and Na\u2010containing sulfides and chlorides by applying thermodynamic analyses based on a first principles computation database. We reveal the stability trends among different chemistries and identify the effect of cations, anions, and Li\/Na content on moisture stability. 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