{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T02:33:56Z","timestamp":1790822036482,"version":"4.1.0"},"reference-count":21,"publisher":"Wiley","issue":"39","license":[{"start":{"date-parts":[[2020,7,28]],"date-time":"2020-07-28T00:00:00Z","timestamp":1595894400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2020,9,21]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    A key challenge in the design of magnetic molecular switches is to obtain bistability at room temperature. Here, we show that application of moderate pressure makes it possible to convert a paramagnetic Fe\n                    <jats:sup>III<\/jats:sup>\n                    <jats:sub>2<\/jats:sub>\n                    Co\n                    <jats:sup>II<\/jats:sup>\n                    <jats:sub>2<\/jats:sub>\n                    square complex into a molecular switch exhibiting a full dia\u2010 to paramagnetic transition: Fe\n                    <jats:sup>II<\/jats:sup>\n                    Co\n                    <jats:sup>III<\/jats:sup>\n                    \u21d4 Fe\n                    <jats:sup>III<\/jats:sup>\n                    Co\n                    <jats:sup>II<\/jats:sup>\n                    . Moreover, the complex follows a rare behavior: the higher the pressure, the broader the magnetic hysteresis. Thus, the application of an adequate pressure allows inducing a magnetic bistability at room temperature with predictable hysteresis width. The structural studies at different pressures suggest that the pressure\u2010enhanced bistability is due to the strengthening of intermolecular interactions upon pressure increase. An original microscopic Ising\u2010like model including pressure effects is developed to simulate this unprecedented behavior. Overall, this study shows that FeCo complexes could be very sensitive piezo switches with potential use as sensors.\n                  <\/jats:p>","DOI":"10.1002\/anie.202008051","type":"journal-article","created":{"date-parts":[[2020,6,22]],"date-time":"2020-06-22T09:11:03Z","timestamp":1592817063000},"page":"17272-17276","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":51,"title":["Pressure\u2010Induced Conversion of a Paramagnetic FeCo Complex into a Molecular Magnetic Switch with Tuneable Hysteresis"],"prefix":"10.1002","volume":"59","author":[{"given":"Yanling","family":"Li","sequence":"first","affiliation":[{"name":"Sorbonne Universit\u00e9 Institut Parisien de Chimie Mol\u00e9culaire CNRS UMR 8232  4 place Jussieu 75252 Paris cedex 5 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Amina","family":"Benchohra","sequence":"additional","affiliation":[{"name":"Sorbonne Universit\u00e9 Institut Parisien de Chimie Mol\u00e9culaire CNRS UMR 8232  4 place Jussieu 75252 Paris cedex 5 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Buqin","family":"Xu","sequence":"additional","affiliation":[{"name":"Sorbonne Universit\u00e9 Institut Parisien de Chimie Mol\u00e9culaire CNRS UMR 8232  4 place Jussieu 75252 Paris cedex 5 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Beno\u00eet","family":"Baptiste","sequence":"additional","affiliation":[{"name":"Sorbonne Universit\u00e9 Institut de Min\u00e9ralogie, de Physique des Mat\u00e9riaux et de Cosmochimie (IMPMC) UMR 7590 CNRS, UMR 206 IRD Museum National d'Histoire Naturelle MNHN  4 place Jussieu 75005 Paris France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Keevin","family":"B\u00e9neut","sequence":"additional","affiliation":[{"name":"Sorbonne Universit\u00e9 Institut de Min\u00e9ralogie, de Physique des Mat\u00e9riaux et de Cosmochimie (IMPMC) UMR 7590 CNRS, UMR 206 IRD Museum National d'Histoire Naturelle MNHN  4 place Jussieu 75005 Paris France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Paraskevas","family":"Parisiades","sequence":"additional","affiliation":[{"name":"Sorbonne Universit\u00e9 Institut de Min\u00e9ralogie, de Physique des Mat\u00e9riaux et de Cosmochimie (IMPMC) UMR 7590 CNRS, UMR 206 IRD Museum National d'Histoire Naturelle MNHN  4 place Jussieu 75005 Paris France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ludovic","family":"Delbes","sequence":"additional","affiliation":[{"name":"Sorbonne Universit\u00e9 Institut de Min\u00e9ralogie, de Physique des Mat\u00e9riaux et de Cosmochimie (IMPMC) UMR 7590 CNRS, UMR 206 IRD Museum National d'Histoire Naturelle MNHN  4 place Jussieu 75005 Paris France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alain","family":"Soyer","sequence":"additional","affiliation":[{"name":"Sorbonne Universit\u00e9 Institut de Min\u00e9ralogie, de Physique des Mat\u00e9riaux et de Cosmochimie (IMPMC) UMR 7590 CNRS, UMR 206 IRD Museum National d'Histoire Naturelle MNHN  4 place Jussieu 75005 Paris France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kamel","family":"Boukheddaden","sequence":"additional","affiliation":[{"name":"Universit\u00e9 Paris-Saclay UVSQ, Groupe d'Etudes de la Mati\u00e8re Condens\u00e9e, CNRS UMR No 8635  45 Avenue des Etats-Unis 78035 Versailles cedex France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3510-5112","authenticated-orcid":false,"given":"Rodrigue","family":"Lescou\u00ebzec","sequence":"additional","affiliation":[{"name":"Sorbonne Universit\u00e9 Institut Parisien de Chimie Mol\u00e9culaire CNRS UMR 8232  4 place Jussieu 75252 Paris cedex 5 France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,7,28]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2017.03.024"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201703862"},{"key":"e_1_2_6_3_1","volume-title":"Spin-Crossover Materials: Properties and Applications","year":"2013"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201807334"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2005.01.022"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.crci.2018.07.010"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201804557"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201804557"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201701194"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201100407"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CC48116F"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6RA00191B"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwy033"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201610268"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201610268"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2008.03.114"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp805852n"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.62.14796"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.9b00776"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja3087467"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.9b00540"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.202008051","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202008051","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202008051","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202008051","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,28]],"date-time":"2023-08-28T13:14:01Z","timestamp":1693228441000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202008051"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,7,28]]},"references-count":21,"journal-issue":{"issue":"39","published-print":{"date-parts":[[2020,9,21]]}},"alternative-id":["10.1002\/anie.202008051"],"URL":"https:\/\/doi.org\/10.1002\/anie.202008051","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,7,28]]},"assertion":[{"value":"2020-06-05","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-07-28","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}