{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T23:24:35Z","timestamp":1788996275635,"version":"build-2803163510"},"reference-count":58,"publisher":"Wiley","issue":"47","license":[{"start":{"date-parts":[[2020,9,9]],"date-time":"2020-09-09T00:00:00Z","timestamp":1599609600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100000266","name":"Engineering and Physical Sciences Research Council","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100000266","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2020,11,16]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Phosphagallenes (<jats:bold>1\u2009a<\/jats:bold>\/<jats:bold>1\u2009b<\/jats:bold>) featuring double bonds between phosphorus and gallium were synthesized by reaction of (phosphanyl)phosphaketenes with the gallium carbenoid Ga(Nacnac) (Nacnac=HC[C(Me)N(2,6\u2010<jats:italic>i<\/jats:italic>\u2010Pr<jats:sub>2<\/jats:sub>C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>)]<jats:sub>2<\/jats:sub>). The stability of these species is dependent on the saturation of the phosphanyl moiety. <jats:bold>1\u2009a<\/jats:bold>, which bears an unsaturated phosphanyl ring, rearranges in solution to yield a spirocyclic compound (<jats:bold>2<\/jats:bold>) which contains a P=P bond. The saturated variant <jats:bold>1\u2009b<\/jats:bold> is stable even at elevated temperatures. <jats:bold>1\u2009b<\/jats:bold> behaves as a frustrated Lewis pair capable of activation of H<jats:sub>2<\/jats:sub> and forms a 1:1 adduct with CO<jats:sub>2<\/jats:sub>.<\/jats:p>","DOI":"10.1002\/anie.202008207","type":"journal-article","created":{"date-parts":[[2020,7,2]],"date-time":"2020-07-02T16:58:52Z","timestamp":1593709132000},"page":"20914-20918","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":76,"title":["A Phosphanyl\u2010Phosphagallene that Functions as a Frustrated Lewis Pair"],"prefix":"10.1002","volume":"59","author":[{"given":"Daniel W. 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