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In this communication, a copper\u2010catalyzed selectivity controlled regiodivergent borocarbonylation of imines with alkyl iodides has been developed. Various \u03b1\u2010amino ketones and \u03b1\u2010boryl amides were produced in moderate to good yields from the same substrates. The choice of the ligand is key for the regioselectivity control: \u03b1\u2010amino ketones were produced selectively in good yields with (<jats:italic>p<\/jats:italic>\u2010CF<jats:sub>3<\/jats:sub>C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub>P as the ligand, whereas the corresponding \u03b1\u2010boryl amides were obtained with high regioselectivities when using <jats:sup>Me<\/jats:sup>IMes as the ligand.<\/jats:p>","DOI":"10.1002\/anie.202012251","type":"journal-article","created":{"date-parts":[[2020,9,29]],"date-time":"2020-09-29T19:53:14Z","timestamp":1601409194000},"page":"695-700","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":50,"title":["Ligand\u2010Controlled Copper\u2010Catalyzed Regiodivergent Carbonylative Synthesis of \u03b1\u2010Amino Ketones and \u03b1\u2010Boryl Amides from Imines and Alkyl Iodides"],"prefix":"10.1002","volume":"60","author":[{"given":"Fu\u2010Peng","family":"Wu","sequence":"first","affiliation":[{"name":"Leibniz-Institut f\u00fcr Katalyse e.V. an der Universit\u00e4t Rostock  Albert-Einstein-Stra\u00dfe 29a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6622-3328","authenticated-orcid":false,"given":"Xiao\u2010Feng","family":"Wu","sequence":"additional","affiliation":[{"name":"Leibniz-Institut f\u00fcr Katalyse e.V. an der Universit\u00e4t Rostock  Albert-Einstein-Stra\u00dfe 29a 18059 Rostock Germany"},{"name":"Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences  116023 Dalian Liaoning China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,11,5]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00068"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c01479"},{"key":"e_1_2_2_4_1","unstructured":"\u00a0"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201804883"},{"key":"e_1_2_2_5_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201804883"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202002714"},{"key":"e_1_2_2_6_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202002714"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c06800"},{"key":"e_1_2_2_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202006427"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202006427"},{"key":"e_1_2_2_9_1","unstructured":"\u00a0"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00816C"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2018.11.006"},{"key":"e_1_2_2_12_2","author":"Cheng J.","year":"2020","journal-title":"Chem. 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