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To this end a Rh\u2010catalyzed desymmetrization of dihydrosilanes by way of intramolecular C(sp<jats:sup>2<\/jats:sup>)\u2212H functionalization under simple and mild conditions has now been developed. This method provides easy access to a broad range of chiral monohydrosilanes in good yields with excellent enantioselectivities (up to &gt;99\u2009% <jats:italic>ee<\/jats:italic>). The resulting monohydrosilanes constitute a good platform to access stereogenic silicon compounds, as well as useful compounds to probe silicon stereochemistry.<\/jats:p>","DOI":"10.1002\/anie.202013041","type":"journal-article","created":{"date-parts":[[2020,11,9]],"date-time":"2020-11-09T03:24:13Z","timestamp":1604892253000},"page":"4245-4251","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":99,"title":["Rhodium\u2010Catalyzed Synthesis of Chiral Monohydrosilanes by Intramolecular C\u2212H Functionalization of Dihydrosilanes"],"prefix":"10.1002","volume":"60","author":[{"given":"Wenpeng","family":"Ma","sequence":"first","affiliation":[{"name":"MOE Key Laboratory of Bioorganic Phosphorus Chemistry &amp; Chemical Biology and School of Pharmaceutical Sciences &amp; Tsinghua-Peking Joint Center for Life Sciences Tsinghua University  Beijing 100084 P. R. 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