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Pyrogallol[5]arenes and resorcin[5]arenes interact with anions via hydrogen bonds involving phenolic OH groups or aromatic CH groups. Based on NMR titration experiments, diffusion coefficients, and geometric requirements, it is postulated that the capsules have (<jats:bold>P5H<\/jats:bold>)<jats:sub>12<\/jats:sub>(X<jats:sup>\u2212<\/jats:sup>)<jats:sub>60<\/jats:sub> or (<jats:bold>R5H<\/jats:bold>)<jats:sub>12<\/jats:sub>(X<jats:sup>\u2212<\/jats:sup>)<jats:sub>60<\/jats:sub> stoichiometry and a unique geometry of one of the Platonic solids\u2014a dodecahedron. The capsules exist in THF and in benzene, but not in chloroform, reflecting competitive effects in the solvation of anions. It is also demonstrated that mechanochemical pre\u2010treatment (dry\u2010milling) of solid samples is indispensable to initialize self\u2010assembly in benzene.<\/jats:p>","DOI":"10.1002\/anie.202013105","type":"journal-article","created":{"date-parts":[[2020,12,29]],"date-time":"2020-12-29T10:44:04Z","timestamp":1609238644000},"page":"4540-4544","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":27,"title":["Dodecameric Anion\u2010Sealed Capsules based on Pyrogallol[5]arenes and Resorcin[5]arenes"],"prefix":"10.1002","volume":"60","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5032-4834","authenticated-orcid":false,"given":"Monika","family":"Chwastek","sequence":"first","affiliation":[{"name":"Institute of Organic Chemistry Polish Academy of Sciences  Kasprzaka 44\/52 Warsaw 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