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Herein, helical 3\u2010aminophenol formaldehyde resin (APF) nanotubes and corresponding carbonaceous nanotubes with controllable handedness and optical activity were obtained via an external metal ion\u2010mediated supramolecular co\u2010templating method in an enantiomerically pure template system, in which an appropriate amount of Mn\n                    <jats:sup>2+<\/jats:sup>\n                    (Co\n                    <jats:sup>2+<\/jats:sup>\n                    or Ni\n                    <jats:sup>2+<\/jats:sup>\n                    ) with moderate coordination abilities can reverse the spatial arrangement of the phenylglycine\u2010based amphiphilic template molecules through metal coordination. Different stacking modes of coordination complexes in disparate metal ion systems lead to diverse helical senses (diameter and pitch) of the obtained helical APF. In addition, this coordination mode of metal intervention can be applied to other amine\u2010based helical polymer synthesis systems, which paves the way for the design of high\u2010quality chiral nanomaterials with satisfactory physical parameters and properties.\n                  <\/jats:p>","DOI":"10.1002\/anie.202013790","type":"journal-article","created":{"date-parts":[[2020,12,27]],"date-time":"2020-12-27T22:07:03Z","timestamp":1609106823000},"page":"7759-7769","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":54,"title":["Handedness Inversion of Chiral 3\u2010Aminophenol Formaldehyde Resin Nanotubes Mediated by Metal Coordination"],"prefix":"10.1002","volume":"60","author":[{"given":"Xinlin","family":"Zha","sequence":"first","affiliation":[{"name":"Hubei Key Laboratory of Advanced Textile Materials &amp; Application Wuhan Textile University  Yangguang Road 1 Wuhan 430200 P. R. 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