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Despite great progress, there is still a great gap to develop an ideal arylation method featuring mild conditions, good functional group tolerance, and readily available starting materials. We now show that electrochemical arylation can fill the gap. By taking advantage of synthetic electrochemistry, commercially available aldehydes (ketones) and benzylic alcohols can be readily arylated to provide a general and scalable access to structurally diverse alcohols (97 examples, &gt;10\u2005gram\u2010scale). More importantly, convergent paired electrolysis, the ideal but challenging electrochemical technology, was employed to transform low\u2010value alcohols into more useful alcohols. Detailed mechanism study suggests that two plausible pathways are involved in the redox neutral \u03b1\u2010arylation of benzylic alcohols.<\/jats:p>","DOI":"10.1002\/anie.202015230","type":"journal-article","created":{"date-parts":[[2020,12,30]],"date-time":"2020-12-30T08:33:30Z","timestamp":1609317210000},"page":"7275-7282","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":148,"title":["Electrochemical Arylation of Aldehydes, Ketones, and Alcohols: from Cathodic Reduction to Convergent Paired Electrolysis"],"prefix":"10.1002","volume":"60","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9686-3921","authenticated-orcid":false,"given":"Sheng","family":"Zhang","sequence":"first","affiliation":[{"name":"Engineering Technology Research Center of Henan Province for Photo- and Electrochemical Catalysis College of Chemistry and Pharmaceutical Engineering Nanyang Normal University  Nanyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lijun","family":"Li","sequence":"additional","affiliation":[{"name":"Engineering Technology Research Center of Henan Province for Photo- and Electrochemical Catalysis College of Chemistry and Pharmaceutical Engineering Nanyang Normal University  Nanyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingjing","family":"Li","sequence":"additional","affiliation":[{"name":"Engineering Technology Research Center of Henan Province for Photo- and Electrochemical Catalysis College of Chemistry and Pharmaceutical Engineering Nanyang Normal University  Nanyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianxue","family":"Shi","sequence":"additional","affiliation":[{"name":"Engineering Technology Research Center of Henan Province for Photo- and Electrochemical Catalysis College of Chemistry and Pharmaceutical Engineering Nanyang Normal University  Nanyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0419-8822","authenticated-orcid":false,"given":"Kun","family":"Xu","sequence":"additional","affiliation":[{"name":"Engineering Technology Research Center of Henan Province for Photo- and Electrochemical Catalysis College of Chemistry and Pharmaceutical Engineering Nanyang Normal University  Nanyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenchao","family":"Gao","sequence":"additional","affiliation":[{"name":"Engineering Technology Research Center of Henan Province for Photo- and Electrochemical Catalysis College of Chemistry and Pharmaceutical Engineering Nanyang Normal University  Nanyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Luyi","family":"Zong","sequence":"additional","affiliation":[{"name":"Engineering Technology Research Center of Henan Province for Photo- and Electrochemical Catalysis College of Chemistry and Pharmaceutical Engineering Nanyang Normal University  Nanyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9312-412X","authenticated-orcid":false,"given":"Guigen","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry Texas Tech University  Lubbock TX 79423 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3738-4039","authenticated-orcid":false,"given":"Michael","family":"Findlater","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry Texas Tech University  Lubbock TX 79423 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,2,24]]},"reference":[{"key":"e_1_2_6_1_1","unstructured":"For application of alcohols in organic synthesis see:"},{"key":"e_1_2_6_2_2","volume-title":"Comprehensive Organic Transformations: A Guide to Functional Group Preparations","author":"Larock R. 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