{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T21:49:14Z","timestamp":1792187354736,"version":"4.4.0"},"reference-count":79,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2021,1,26]],"date-time":"2021-01-26T00:00:00Z","timestamp":1611619200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2021,2,15]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    We present a metal docking strategy utilizing the precise spatial arrangement of organic struts as metal chelating sites in a MOF. Pairs of uncoordinated N\u2005atoms on adjacent pyrazole dicarboxylate linkers distributed along the rod\u2010shaped Al\u2013O secondary building units in MOF\u2010303 [Al(OH)(C\n                    <jats:sub>5<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )] were used to chelate Cu\n                    <jats:sup>I<\/jats:sup>\n                    and Ag\n                    <jats:sup>I<\/jats:sup>\n                    with atomic precision and yield the metalated Cu\u2010 and Ag\u2010MOF\u2010303 compounds [(CuCl)\n                    <jats:sub>0.50<\/jats:sub>\n                    Al(OH)(C\n                    <jats:sub>5<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    ) and (AgNO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>0.49<\/jats:sub>\n                    Al(OH)(C\n                    <jats:sub>5<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )]. The coordination geometries of Cu\n                    <jats:sup>I<\/jats:sup>\n                    and Ag\n                    <jats:sup>I<\/jats:sup>\n                    were examined using 3D electron diffraction and extended X\u2010ray absorption fine structure spectroscopy techniques. The resulting metalated MOFs showed pore sizes matching the size of Xe, thus allowing for binding of Xe from Xe\/Kr mixtures with high capacity and selectivity. In particular, Ag\u2010MOF\u2010303 exhibited Xe uptake of 59\u2005cm\n                    <jats:sup>3<\/jats:sup>\n                    \u2009cm\n                    <jats:sup>\u22123<\/jats:sup>\n                    at 298\u2005K and 0.2\u2005bar with a selectivity of 10.4, placing it among the highest performing MOFs.\n                  <\/jats:p>","DOI":"10.1002\/anie.202015262","type":"journal-article","created":{"date-parts":[[2020,11,28]],"date-time":"2020-11-28T00:23:46Z","timestamp":1606523026000},"page":"3417-3421","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":198,"title":["Docking of Cu\n                    <sup>I<\/sup>\n                    and Ag\n                    <sup>I<\/sup>\n                    in Metal\u2013Organic Frameworks for Adsorption and Separation of Xenon"],"prefix":"10.1002","volume":"60","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6961-6554","authenticated-orcid":false,"given":"Haoze","family":"Wang","sequence":"first","affiliation":[{"name":"Department of Chemistry University of California-Berkeley  Berkeley CA 94720 USA"},{"name":"Kavli Energy NanoSciences Institute  Berkeley CA 94720 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9698-4152","authenticated-orcid":false,"given":"Zhaolin","family":"Shi","sequence":"additional","affiliation":[{"name":"School of Physical Science and Technology ShanghaiTech University  Shanghai 201210 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1192-7368","authenticated-orcid":false,"given":"Jingjing","family":"Yang","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of California-Berkeley  Berkeley CA 94720 USA"},{"name":"Kavli Energy NanoSciences 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