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In contrast, the synthesis of compounds containing homo\u2010 or hetero\u2010nuclear multiple bonds involving s\u2010block elements is extremely rare. Herein, we report the synthesis, molecular structure, and computational analysis of a beryllium imido (Be=N) complex (<jats:bold>2<\/jats:bold>), which was prepared via oxidation of a molecular Be<jats:sup>0<\/jats:sup>precursor (<jats:bold>1<\/jats:bold>) with trimethylsilyl azide Me<jats:sub>3<\/jats:sub>SiN<jats:sub>3<\/jats:sub>(TMS\u2010N<jats:sub>3<\/jats:sub>). Notably, compound<jats:bold>2<\/jats:bold>features the shortest known Be=N bond (1.464\u2005\u00c5) to date. This represents the first compound with an s\u2010block metal\u2010nitrogen multiple bond. All compounds were characterized experimentally with multi\u2010nuclear NMR spectroscopy (<jats:sup>1<\/jats:sup>H,<jats:sup>13<\/jats:sup>C,<jats:sup>9<\/jats:sup>Be) and single\u2010crystal X\u2010ray diffraction studies. The bonding situation was analyzed with density functional theory (DFT) calculations, which supports the existence of \u03c0\u2010bonding between beryllium and nitrogen.<\/jats:p>","DOI":"10.1002\/anie.202016027","type":"journal-article","created":{"date-parts":[[2021,1,10]],"date-time":"2021-01-10T22:29:50Z","timestamp":1610317790000},"page":"9407-9411","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":39,"title":["s\u2010Block Multiple Bonds: Isolation of a Beryllium Imido Complex"],"prefix":"10.1002","volume":"60","author":[{"given":"Guocang","family":"Wang","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Virginia 409 McCormick Rd.\/ PO Box 400319 Charlottesville VA 22904 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jacob E.","family":"Walley","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Virginia 409 McCormick Rd.\/ PO Box 400319 Charlottesville VA 22904 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Diane A.","family":"Dickie","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Virginia 409 McCormick Rd.\/ PO Box 400319 Charlottesville VA 22904 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrew","family":"Molino","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Physics La Trobe Institute for Molecular Science La Trobe University Melbourne Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"David J. 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