{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T21:05:39Z","timestamp":1791320739578,"version":"4.3.1"},"reference-count":70,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2021,2,15]],"date-time":"2021-02-15T00:00:00Z","timestamp":1613347200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["NI1095\/8-1"],"award-info":[{"award-number":["NI1095\/8-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100009375","name":"Graduate School, Technische Universit\u00e4t M\u00fcnchen","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100009375","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2021,3,15]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Phosphorene\u2014the monolayered material of the element allotrope black phosphorus (P<jats:sub>black<\/jats:sub>)\u2014and SnIP are 2D and 1D semiconductors with intriguing physical properties. P<jats:sub>black<\/jats:sub> and SnIP have in common that they can be synthesized via short way transport or mineralization using tin, tin(IV) iodide and amorphous red phosphorus. This top\u2010down approach is the most important access route to phosphorene. The two preparation routes are closely connected and differ mainly in reaction temperature and molar ratios of starting materials. Many speculative intermediates or activator side phases have been postulated especially for top\u2010down P<jats:sub>black<\/jats:sub>\/phosphorene synthesis, such as Hittorf's phosphorus or Sn<jats:sub>24<\/jats:sub>P<jats:sub>19.3<\/jats:sub>I<jats:sub>8<\/jats:sub> clathrate. The importance of phosphorus\u2010based 2D and 1D materials for energy conversion, storage, and catalysis inspired us to elucidate the formation mechanisms of these two compounds. Herein, we report on the reaction mechanisms of P<jats:sub>black<\/jats:sub>\/phosphorene and SnIP from P<jats:sub>4<\/jats:sub> and SnI<jats:sub>2<\/jats:sub> via direct gas phase formation.<\/jats:p>","DOI":"10.1002\/anie.202016257","type":"journal-article","created":{"date-parts":[[2021,1,29]],"date-time":"2021-01-29T11:58:26Z","timestamp":1611921506000},"page":"6816-6823","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":36,"title":["Formation Mechanisms for Phosphorene and SnIP"],"prefix":"10.1002","volume":"60","author":[{"given":"Markus R. P.","family":"Pielmeier","sequence":"first","affiliation":[{"name":"Department of Chemistry Technical University of Munich (TUM)  Lichtenbergstrasse 4 85748 Garching b. M\u00fcnchen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1415-4265","authenticated-orcid":false,"given":"Tom","family":"Nilges","sequence":"additional","affiliation":[{"name":"Department of Chemistry Technical University of Munich (TUM)  Lichtenbergstrasse 4 85748 Garching b. M\u00fcnchen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,2,15]]},"reference":[{"key":"e_1_2_6_1_1","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1515\/zkri-2014-1800"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201404147"},{"key":"e_1_2_6_3_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201404147"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja02184a002"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja02260a008"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1088\/2053-1583\/1\/2\/025001"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201703585"},{"key":"e_1_2_6_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201703585"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201703876"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.3389\/fchem.2019.00021"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-16077-z"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.9b04741"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201106479"},{"key":"e_1_2_6_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201106479"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201811152"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201811152"},{"key":"e_1_2_6_14_1","unstructured":"\u00a0"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/nn501226z"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcrysgro.2014.07.029"},{"key":"e_1_2_6_17_1","unstructured":"\u00a0"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl502928y"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.6b01977"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/jz501188k"},{"key":"e_1_2_6_21_1","unstructured":"\u00a0"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/nn505868h"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2014.35"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201500990"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl5047329"},{"key":"e_1_2_6_26_1","unstructured":"\u00a0"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.3390\/nano6110194"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2016.02.094"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201900233"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9NA00084D"},{"key":"e_1_2_6_31_1","unstructured":"\u00a0"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1800069115"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl504336h"},{"key":"e_1_2_6_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn5059248"},{"key":"e_1_2_6_35_1","author":"Zhao S.","journal-title":"arXiv"},{"key":"e_1_2_6_36_1","unstructured":"CVD and Vapor deposition:"},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201703748"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1088\/0957-4484\/27\/21\/215602"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.0c00746"},{"key":"e_1_2_6_40_1","unstructured":"\u00a0"},{"key":"e_1_2_6_41_2","unstructured":"T.Nilges D.Pfister C.Ott K.Sch\u00e4fer M.Baumgartner R.Weihrich(TUM)EP 3 319 903 B1 2015;"},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201603135"},{"key":"e_1_2_6_43_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic990153r"},{"key":"e_1_2_6_44_1","unstructured":"\u00a0"},{"key":"e_1_2_6_45_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcrysgro.2017.07.015"},{"key":"e_1_2_6_46_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.0c02079"},{"key":"e_1_2_6_47_1","unstructured":"\u00a0"},{"key":"e_1_2_6_48_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201700231"},{"key":"e_1_2_6_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.7b01239"},{"key":"e_1_2_6_50_1","unstructured":"\u00a0"},{"key":"e_1_2_6_51_2","unstructured":"M.\u2005J. Frisch G.\u2005W. Trucks H.\u2005B. Schlegel G.\u2005E. Scuseria M.\u2005A. Robb J.\u2005R. Cheeseman G. Scalmani V. Barone G.\u2005A. Petersson H. Nakatsuji X. Li M. Caricato A.\u2005V. Marenich J. Bloino Gaussian 09 Revision E.01 Gaussian Inc. : Wallingford CT 2013;"},{"key":"e_1_2_6_52_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.77.3865"},{"key":"e_1_2_6_53_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.434039"},{"key":"e_1_2_6_54_2","doi-asserted-by":"publisher","DOI":"10.1080\/00268978800101811"},{"key":"e_1_2_6_55_2","unstructured":"R. Dennington T. Keith J. Millam GaussView Version 5 2013."},{"key":"e_1_2_6_56_1","unstructured":"GMIN Version 5.1 Package TRAGMIN for Calculation of Thermodynamic Equilibrium www.tragmin.de(accessed: September 2020)."},{"key":"e_1_2_6_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic062192q"},{"key":"e_1_2_6_58_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11669-018-0671-y"},{"key":"e_1_2_6_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/pssb.201700426"},{"key":"e_1_2_6_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19120790113"},{"key":"e_1_2_6_61_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2052520617001901"},{"key":"e_1_2_6_62_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CE01608A"},{"key":"e_1_2_6_63_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201501758"},{"key":"e_1_2_6_64_1","unstructured":"\u00a0"},{"key":"e_1_2_6_65_2","unstructured":"Seamless steel tubes for oil- and water-hydraulic systems\u2014Calculation rules for pipes and elbows for dynamic loads. DIN 2413:2020-04: Deutsches Institut f\u00fcr Normung e.V.;"},{"key":"e_1_2_6_66_2","unstructured":"Fused silica knowledge base. Heraeus Holding GmbH:https:\/\/www.heraeus.com\/en\/hca\/fused\u2002silica\u2002quartz\u2002knowledge\u2002base\u20021\/properties\u20021\/properties\u2002hca.html#tabs-608478-6."}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202016257","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202016257","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202016257","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,2]],"date-time":"2023-09-02T02:30:51Z","timestamp":1693621851000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202016257"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,2,15]]},"references-count":70,"journal-issue":{"issue":"12","published-print":{"date-parts":[[2021,3,15]]}},"alternative-id":["10.1002\/anie.202016257"],"URL":"https:\/\/doi.org\/10.1002\/anie.202016257","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,2,15]]},"assertion":[{"value":"2020-12-08","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2021-02-15","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}