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The starting nitroso derivatives are readily prepared by oxidation of the corresponding oximes prepared from ketones and the overall transformation represents an oxidative coupling of a ketone with a Michael acceptor. The cascade proceeds smoothly under mild conditions, providing a series of valuable functionalized oximes in moderate to good yields. Mechanistic studies suggest that these cascades proceed via addition\/coupling processes that are controlled by the persistent radical effect (PRE) with NO acting as the persistent species.<\/jats:p>","DOI":"10.1002\/anie.202016955","type":"journal-article","created":{"date-parts":[[2021,2,10]],"date-time":"2021-02-10T06:02:57Z","timestamp":1612936977000},"page":"8547-8551","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":40,"title":["Photo\u2010Mediated Intermolecular Coupling of Alkenes with Ketones via Acyloxy Nitroso Compounds"],"prefix":"10.1002","volume":"60","author":[{"given":"Danqing","family":"Zheng","sequence":"first","affiliation":[{"name":"Westf\u00e4lische Wilhelms-Universit\u00e4t Organisch-Chemisches Institut Corrensstrasse 40 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stefanie","family":"Pl\u00f6ger","sequence":"additional","affiliation":[{"name":"Westf\u00e4lische Wilhelms-Universit\u00e4t Organisch-Chemisches Institut Corrensstrasse 40 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Constantin G.","family":"Daniliuc","sequence":"additional","affiliation":[{"name":"Westf\u00e4lische Wilhelms-Universit\u00e4t Organisch-Chemisches Institut Corrensstrasse 40 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1706-513X","authenticated-orcid":false,"given":"Armido","family":"Studer","sequence":"additional","affiliation":[{"name":"Westf\u00e4lische Wilhelms-Universit\u00e4t Organisch-Chemisches Institut Corrensstrasse 40 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,2,25]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00278"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b08856"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/9781119953678"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201505090"},{"key":"e_1_2_2_5_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201505090"},{"key":"e_1_2_2_6_2","doi-asserted-by":"crossref","DOI":"10.1093\/oso\/9780198502418.001.0001","volume-title":"Radical Reactions in Organic Synthesis","author":"Zard S. 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