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A large number of aryl and alkyl isocyanates, including electron\u2010donating and withdrawing groups, undergo reduction to obtain selectively N\u2010boryl formamide, bis(boryl) hemiaminal and N\u2010boryl methyl amine products. The compound<jats:bold>I<\/jats:bold>effectively catalyzes the chemoselective reduction of various isocyanates, in which the construction of the amide bond occurs. Isocyanates undergo a deoxygenation hydroboration reaction, in which the C=O bond cleaves, leading to N\u2010boryl methyl amines. Several functionalities such as nitro, cyano, halide, and alkene groups are well\u2010tolerated. 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