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Two different families of unsymmetrically substituted Zn phthalocyanines (Pc) absorbing in the 700\u2013800\u2005nm spectral window and containing a fused imidazole\u2010phenyl substituent or a fused imidazole\u2010hydroxyphenyl group have been synthetized and characterized as a bioinspired model of the Chl<jats:italic>f<\/jats:italic>\/Tyrosine<jats:sub>Z<\/jats:sub>\/Histidine<jats:sub>190<\/jats:sub> cofactors of PSII. Transient absorption studies in the presence of an electron acceptor and irradiating in the far\u2010red region evidenced an intramolecular electron transfer process. Visible and FT\u2010IR signatures indicate the formation of a hydrogen\u2010bonded phenoxyl radical in ZnPc II\u2010OH. 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