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However, corrosion and dissolution of organic crystals by solvents have always been a great challenge for the application of organic crystals in various fields. In this work, we propose a general method of fabricating a solvent\u2010resistant coating to prevent organic crystals from being corroded or dissolved by organic solvents. The coatings involved layer\u2010by\u2010layer assembly of poly(diallyldimethylammonium) (PDDA) and poly(styrenesulfonate) (PSS) onto crystals, followed by immersing the coated crystals into polyvinyl alcohol (PVA) aqueous solutions for 2\u2005minutes. The coated crystals can remain intact over 24\u2005h in common organic solvents without being damaged and even insoluble in dichloromethane for 5\u2005days. Moreover, the thin and transparent coatings have little effect on the optical properties of crystals which still have excellent optical waveguide performance with the coatings.<\/jats:p>","DOI":"10.1002\/anie.202102285","type":"journal-article","created":{"date-parts":[[2021,3,10]],"date-time":"2021-03-10T03:14:16Z","timestamp":1615346056000},"page":"11283-11287","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":49,"title":["Polymer\u2010Coated Organic Crystals with Solvent\u2010Resistant Capacity and Optical Waveguiding Function"],"prefix":"10.1002","volume":"60","author":[{"given":"Linfeng","family":"Lan","sequence":"first","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials College of Chemistry Jilin University  Qianjin Street Changchun P. R. 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