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All reactions proceed efficiently at room temperature using air as sole oxidant. This transformation has been applied to a variety of substrates, is operationally simple, proceeds under mild reaction conditions, and shows a high functional\u2010group tolerance. The ketones are formed smoothly in up to 97\u2009% yield and with 100\u2009% regioselectivity, while the corresponding alcohols were observed as by\u2010products. Labeling experiments showed that an incorporated hydrogen atom originates from the phenylsilane. The oxygen atom of the ketone as well as of the alcohol derives from the ambient atmosphere.\n                  <\/jats:p>","DOI":"10.1002\/anie.202103222","type":"journal-article","created":{"date-parts":[[2021,4,15]],"date-time":"2021-04-15T20:12:39Z","timestamp":1618517559000},"page":"14083-14090","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":65,"title":["Iron\u2010Catalyzed Wacker\u2010type Oxidation of Olefins at Room Temperature with 1,3\u2010Diketones or Neocuproine as Ligands**"],"prefix":"10.1002","volume":"60","author":[{"given":"Florian","family":"Puls","sequence":"first","affiliation":[{"name":"Fakult\u00e4t Chemie und Lebensmittelchemie Technische Universit\u00e4t Dresden  Bergstrasse 66 01069 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Philipp","family":"Linke","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t Chemie und Lebensmittelchemie Technische Universit\u00e4t Dresden  Bergstrasse 66 01069 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Olga","family":"Kataeva","sequence":"additional","affiliation":[{"name":"A. E. Arbuzov Institute of Organic and Physical Chemistry FRC Kazan Scientific Center Russian Academy of Sciences  Arbuzov Str. 8 Kazan 420088 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9631-5239","authenticated-orcid":false,"given":"Hans\u2010Joachim","family":"Kn\u00f6lker","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t Chemie und Lebensmittelchemie Technische Universit\u00e4t Dresden  Bergstrasse 66 01069 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,5,14]]},"reference":[{"key":"e_1_2_6_1_1","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527619405"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/9781119942863"},{"key":"e_1_2_6_4_1","unstructured":"\u00a0"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527631582"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2017.04.012"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527699087"},{"key":"e_1_2_6_8_1","unstructured":"\u00a0"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr040664h"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527623273"},{"key":"e_1_2_6_11_2","first-page":"1","volume-title":"Topics in Organometallic Chemistry, Vol.\u200550","author":"Bauer E.","year":"2015"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr500425u"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.6b00272"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00772"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.3390\/molecules25061349"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201603777"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201603777"},{"key":"e_1_2_6_17_1","unstructured":"\u00a0"},{"key":"e_1_2_6_18_2","unstructured":"In the preparation of pharmaceuticals the contamination by palladium must be less than 10\u2005ppm. 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For comparison see:"},{"key":"e_1_2_6_82_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF00752705"},{"key":"e_1_2_6_83_1","unstructured":"Crystallographic data for Fe(dmm)3: C63H69FeO6 M=978.03\u2005g\u2009mol\u22121 crystal size: 0.069\u00d70.122\u00d70.311\u2005mm3 monoclinic space groupP21\/n a=15.910(2) b=17.615(2) c=19.133(2)\u2005\u00c5 \u03b2=92.430(5)\u00b0 V=5357.3(12)\u2005\u00c53 Z=4 \u03c1calcd=1.213\u2005g\u2009cm\u22123 \u03bc=0.332\u2005mm\u22121 \u03bb=0.71073\u2005\u00c5 T=150(2)\u2005K \u03b8\u2005range: 1.57\u201327.55\u00b0 reflections collected: 102\u2009448 independent: 12\u2009322 (Rint=0.0833) 649 parameters. The structure was solved by direct methods and refined by full-matrix least-squares onF2; finalR\u2005indices [I>2\u03c3(I)]:R1=0.0456 wR2=0.0981; maximal residual electron density: 0.327\u2005e\u2009\u00c5\u22123.Deposition Number 2064664contains the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures servicewww.ccdc.cam.ac.uk\/structures."},{"key":"e_1_2_6_84_1","unstructured":"Crystallographic data for Fe(ab)3: C63H63FeO9\u22c5CH2Cl2 M=1068.88\u2005g\u2009mol\u22121 crystal size: 0.251\u00d70.215\u00d70.136\u2005mm3 monoclinic space groupC2\/c a=35.6827(12) b=12.8286(4) c=30.7195(11)\u2005\u00c5 \u03b2=110.2530(12)\u00b0 V=13192.7(8)\u2005\u00c53 Z=8 \u03c1calcd=1.076\u2005g\u2009cm3 \u03bc=0.357\u2005mm\u22121 \u03bb=0.71073\u2005\u00c5 T=150(2)\u2005K \u03b8\u2005range: 2.34\u201326.82\u00b0 reflections collected: 100\u2009690 independent: 16\u2009346 (Rint=0.0730) 668 parameters. 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