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We have developed an efficient, modular, and enantioselective approach towards accessing novel variants of these reagents through Cu\/Pd\u2010catalyzed alkenylboration of alkenylboron derivatives. Importantly, we demonstrate novel use of an allylBdan reagent directly in a stereocontrolled allylation without initial deprotection to the boronic ester. These allylation products are employed in a second intermolecular allylation to access complex diol motifs, which has yet to be shown with these types of double\u2010allylation reagents. 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