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Although CeO<jats:sub>2<\/jats:sub> has been shown to catalyze this reaction, cerium is low in natural abundance and has a narrow global distribution (&gt;90\u2009% of these reserves are located within six countries). It is thus imperative to find another element\/material with high worldwide abundance that can also efficiently extract the phosphate out of agricultural waste for phosphorus recycle. Using <jats:italic>para<\/jats:italic>\u2010nitrophenyl phosphate (<jats:italic>p<\/jats:italic>\u2010NPP) as a model compound, we demonstrate that TiO<jats:sub>2<\/jats:sub> with a F\u2010modified (001) surface can activate <jats:italic>p<\/jats:italic>\u2010NPP dephosphorylation at temperatures as low as 40\u2009\u00b0C. By probe\u2010assisted nuclear magnetic resonance (NMR), it was revealed that the strong electron\u2010withdrawing effect of fluorine makes Ti atoms (the active sites) on the (001) surface very acidic. The bidentate adsorption of <jats:italic>p<\/jats:italic>\u2010NPP on this surface further promotes its subsequent activation with a barrier \u224820\u2005kJ\u2009mol<jats:sup>\u22121<\/jats:sup> lower than that of the pristine (001) and (101) surfaces, allowing the activation of this reaction near room temperature (from &gt;80\u2009\u00b0C).<\/jats:p>","DOI":"10.1002\/anie.202104397","type":"journal-article","created":{"date-parts":[[2021,5,12]],"date-time":"2021-05-12T07:36:06Z","timestamp":1620804966000},"page":"16149-16155","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":30,"title":["Electronic\u2010State Manipulation of Surface Titanium Activates Dephosphorylation Over TiO<sub>2<\/sub> Near Room Temperature"],"prefix":"10.1002","volume":"60","author":[{"given":"Quan","family":"Wang","sequence":"first","affiliation":[{"name":"Department of Chemistry City University of Hong Kong  Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xianfeng","family":"Yi","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics National Center for Magnetic Resonance in Wuhan Key Laboratory of Magnetic Resonance in Biological Systems Wuhan Institute of Physics and Mathematics Innovation Academy for Precision Measurement Science and Technology Chinese Academy of Sciences  Wuhan 430071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu\u2010Cheng","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering City University of Hong Kong  Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yao","family":"Xiao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics National Center for Magnetic Resonance in Wuhan Key Laboratory of Magnetic Resonance in Biological Systems Wuhan Institute of Physics and Mathematics Innovation Academy for Precision Measurement Science and Technology Chinese Academy of Sciences  Wuhan 430071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anmin","family":"Zheng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics National Center for Magnetic Resonance in Wuhan Key Laboratory of Magnetic Resonance in Biological Systems Wuhan Institute of Physics and Mathematics Innovation Academy for Precision Measurement Science and Technology Chinese Academy of Sciences  Wuhan 430071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian Lin","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Science School of Science and Technology The Open University of Hong Kong  Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9590-6902","authenticated-orcid":false,"given":"Yung\u2010Kang","family":"Peng","sequence":"additional","affiliation":[{"name":"Department of Chemistry City University of Hong Kong  Hong Kong SAR China"},{"name":"City University of Hong Kong Shenzhen Research Institute  Shenzhen 518057 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,6,14]]},"reference":[{"key":"e_1_2_6_1_1","volume-title":"Chemistry of the Elements","author":"Greenwood N. 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