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We have designed and synthesized a stable crystalline single\u2010chain catalyst model system for electrochemical CO<jats:sub>2<\/jats:sub>RR, which involves four homomorphic one\u2010dimensional chain\u2010like compounds (<jats:bold>Cu\u2010PzH<\/jats:bold>, <jats:bold>Cu\u2010PzCl<\/jats:bold>, <jats:bold>Cu\u2010PzBr<\/jats:bold>, and <jats:bold>Cu\u2010PzI<\/jats:bold>). The main structural difference of these four chains is the substituents of halogen atoms with different electronegativity on the Pz ligands. Consequently, different synergistic effects between bi\u2010copper centers lead to changes in the faradic efficiency (FE<jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/anie202105343-math-0001.png\" xlink:title=\"urn:x-wiley:14337851:media:anie202105343:anie202105343-math-0001\"\/>\n:FE<jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/anie202105343-math-0002.png\" xlink:title=\"urn:x-wiley:14337851:media:anie202105343:anie202105343-math-0002\"\/>\n). This work provides a simple and stable crystalline single\u2010chain model system for systematically studying the influence of coordination microenvironment on catalytically active centers in the CO<jats:sub>2<\/jats:sub>RR.<\/jats:p>","DOI":"10.1002\/anie.202105343","type":"journal-article","created":{"date-parts":[[2021,6,24]],"date-time":"2021-06-24T02:15:32Z","timestamp":1624500932000},"page":"19829-19835","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":154,"title":["Partial Coordination\u2010Perturbed Bi\u2010Copper Sites for Selective Electroreduction of CO<sub>2<\/sub> to Hydrocarbons"],"prefix":"10.1002","volume":"60","author":[{"given":"Rui","family":"Wang","sequence":"first","affiliation":[{"name":"Jiangsu Key Laboratory of Biofunctional Materials School of Chemistry and Materials Science Nanjing Normal University  Nanjing 210023 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiang","family":"Liu","sequence":"additional","affiliation":[{"name":"Jiangsu Key Laboratory of Biofunctional Materials School of Chemistry and Materials Science Nanjing Normal University  Nanjing 210023 P. R. China"},{"name":"School of Chemistry South China Normal University  Guangzhou 510006 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qing","family":"Huang","sequence":"additional","affiliation":[{"name":"School of Chemistry South China Normal University  Guangzhou 510006 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Long\u2010Zhang","family":"Dong","sequence":"additional","affiliation":[{"name":"Jiangsu Key Laboratory of Biofunctional Materials School of Chemistry and Materials Science Nanjing Normal University  Nanjing 210023 P. R. 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