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Especially, the asymmetric \u03b1\u2010arylation of acyclic aldehydes is a long\u2010standing challenge, because of the highest activity among carbonyl compounds leading to various competitive side reactions. Herein we reported an efficient Pd\u2010catalyzed asymmetric intermolecular \u03b1\u2010arylation reaction of \u03b1\u2010alkyl\u2010\u03b1\u2010aryl disubstituted aldehydes with aryl bromides, which provides a rapid access to chiral aldehydes bearing an \u03b1\u2010all\u2010carbon quaternary stereocenter in moderate to good yields with good er in most cases. 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