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Photons are traceless reagents that provide an exclusive opportunity to alter chemoselectivity of the photocatalytic reaction varying the color of incident light. This strategy may be implemented by using a sensitizer capable to activate a specific reaction pathway depending on the excitation light. Herein, we use potassium poly(heptazine imide) (K\u2010PHI), a type of carbon nitride, to generate selectively three different products from S\u2010arylthioacetates simply varying the excitation light and otherwise identical conditions. Namely, arylchlorides are produced under UV\/purple, sulfonyl chlorides with blue\/white, and diaryldisulfides at green to red light. A combination of the negatively charged polyanion, highly positive potential of the valence band, presence of intraband states, ability to sensitize singlet oxygen, and multi\u2010electron transfer is shown to enable this chromoselective conversion of thioacetates.<\/jats:p>","DOI":"10.1002\/anie.202106183","type":"journal-article","created":{"date-parts":[[2021,7,5]],"date-time":"2021-07-05T08:10:59Z","timestamp":1625472659000},"page":"20543-20550","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":55,"title":["Chromoselective Synthesis of Sulfonyl Chlorides and Sulfonamides with Potassium Poly(heptazine imide) Photocatalyst"],"prefix":"10.1002","volume":"60","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1638-0816","authenticated-orcid":false,"given":"Yevheniia","family":"Markushyna","sequence":"first","affiliation":[{"name":"Department of Colloid Chemistry Max Planck Institute of Colloids and Interfaces  Am M\u00fchlenberg 1 14476 Potsdam Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8116-3802","authenticated-orcid":false,"given":"Christoph M.","family":"Sch\u00fc\u00dflbauer","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Pharmacy Interdisciplinary Center for Molecular Materials(ICMM) Friedrich-Alexander University of Erlangen-N\u00fcrnberg  Egerlandstrasse 3 91058 Erlangen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tobias","family":"Ullrich","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Pharmacy Interdisciplinary Center for Molecular Materials(ICMM) Friedrich-Alexander University of Erlangen-N\u00fcrnberg  Egerlandstrasse 3 91058 Erlangen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3960-1765","authenticated-orcid":false,"given":"Dirk M.","family":"Guldi","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Pharmacy Interdisciplinary Center for Molecular Materials(ICMM) Friedrich-Alexander University of Erlangen-N\u00fcrnberg  Egerlandstrasse 3 91058 Erlangen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8395-7558","authenticated-orcid":false,"given":"Markus","family":"Antonietti","sequence":"additional","affiliation":[{"name":"Department of Colloid Chemistry Max Planck Institute of Colloids and Interfaces  Am M\u00fchlenberg 1 14476 Potsdam Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5760-6033","authenticated-orcid":false,"given":"Aleksandr","family":"Savateev","sequence":"additional","affiliation":[{"name":"Department of Colloid Chemistry Max Planck Institute of Colloids and Interfaces  Am M\u00fchlenberg 1 14476 Potsdam Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,8,8]]},"reference":[{"key":"e_1_2_6_1_1","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.2174\/1568026615666150915111741"},{"key":"e_1_2_6_3_2","first-page":"1","volume-title":"Biotechnology of Aroma Compounds. 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