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We have synthesized a unique Cu\n                    <jats:sup>I<\/jats:sup>\n                    \/Cu\n                    <jats:sup>II<\/jats:sup>\n                    mixed valence copper\u2010based framework {[(Cu\n                    <jats:sup>I<\/jats:sup>\n                    <jats:sub>6<\/jats:sub>\n                    I\n                    <jats:sub>5<\/jats:sub>\n                    )Cu\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>II<\/jats:sup>\n                    L\n                    <jats:sub>6<\/jats:sub>\n                    (DMA)\n                    <jats:sub>3<\/jats:sub>\n                    ](NO\n                    <jats:sub>3<\/jats:sub>\n                    )\u22c59DMA}\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    (\n                    <jats:bold>1<\/jats:bold>\n                    ) with good solvent and thermal stability, as well as a high density of uncoordinated amino groups evenly distributed in the large nanoscopic channels. Catalytic experiments show that\n                    <jats:bold>1<\/jats:bold>\n                    can effectively catalyze the reaction of propargylamines with CO\n                    <jats:sub>2<\/jats:sub>\n                    , and the yield can reach 99\u2009%. The turnover frequency (TOF) reaches a record value of 230\u2005h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , which is much higher than that of reported noble\u2010metal catalysts. Importantly, this is the first report of heterogeneously catalyzed green conversion of propargylamines with CO\n                    <jats:sub>2<\/jats:sub>\n                    without solvents and co\u2010catalysts under low temperature and atmospheric pressure. A mechanistic study reveals that a triply synergistic catalytic effect between Cu\n                    <jats:sup>I<\/jats:sup>\n                    \/Cu\n                    <jats:sup>II<\/jats:sup>\n                    and uncoordinated amino groups promotes highly efficient and green conversion of CO\n                    <jats:sub>2<\/jats:sub>\n                    . Furthermore,\n                    <jats:bold>1<\/jats:bold>\n                    directly catalyzes this reaction with high efficiency when using simulated flue gas as a CO\n                    <jats:sub>2<\/jats:sub>\n                    source.\n                  <\/jats:p>","DOI":"10.1002\/anie.202106773","type":"journal-article","created":{"date-parts":[[2021,6,30]],"date-time":"2021-06-30T04:59:34Z","timestamp":1625029174000},"page":"20417-20423","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":154,"title":["Green Conversion of CO\n                    <sub>2<\/sub>\n                    and Propargylamines Triggered by Triply Synergistic Catalytic Effects in Metal\u2013Organic Frameworks"],"prefix":"10.1002","volume":"60","author":[{"given":"Xiao\u2010Lei","family":"Jiang","sequence":"first","affiliation":[{"name":"Department of Chemistry Key Laboratory of Advanced Energy Material Chemistry MOE, Renewable Energy Conversion and Storage Center (RECAST) Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yue\u2010E","family":"Jiao","sequence":"additional","affiliation":[{"name":"Department of Chemistry Key Laboratory of Advanced Energy Material Chemistry MOE, Renewable Energy Conversion and Storage Center (RECAST) Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sheng\u2010Li","family":"Hou","sequence":"additional","affiliation":[{"name":"Department of Chemistry Key Laboratory of Advanced Energy Material Chemistry MOE, Renewable Energy Conversion and Storage Center (RECAST) Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liang\u2010Chen","family":"Geng","sequence":"additional","affiliation":[{"name":"Department of Chemistry Key Laboratory of Advanced Energy Material Chemistry MOE, Renewable Energy Conversion and Storage Center (RECAST) Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao\u2010Zhe","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry Key Laboratory of Advanced Energy Material Chemistry MOE, Renewable Energy Conversion and Storage Center (RECAST) Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9003-9731","authenticated-orcid":false,"given":"Bin","family":"Zhao","sequence":"additional","affiliation":[{"name":"Department of Chemistry Key Laboratory of Advanced Energy Material Chemistry MOE, Renewable Energy Conversion and Storage Center (RECAST) Nankai University  Tianjin 300071 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