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This reaction generates \u03b2\u2010substituted ketones in an asymmetric manner through a branch\u2010selective decarboxylative allylation pathway. The reaction accommodates various alkoxyallenes as well as amidoallenes.<\/jats:p>","DOI":"10.1002\/anie.202107990","type":"journal-article","created":{"date-parts":[[2021,7,19]],"date-time":"2021-07-19T06:03:34Z","timestamp":1626674614000},"page":"22166-22171","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Palladium\u2010Catalyzed Asymmetric Decarboxylative Addition of \u03b2\u2010Keto Acids to Heteroatom\u2010Substituted Allenes"],"prefix":"10.1002","volume":"60","author":[{"given":"Dong\u2010Jin","family":"Jang","sequence":"first","affiliation":[{"name":"Department of Chemistry Pohang University of Science and Technology  Cheongam-ro 77, Nam-gu Pohang Gyeongbuk 37673 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sukhyun","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Chemistry Pohang University of Science and Technology  Cheongam-ro 77, Nam-gu 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