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In this study, we developed an electrochemical method to synthesize a C\u2212N bond\u2010containing molecule avoiding the use of cyanides and amines by harnessing nitrate (NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) as a nitrogen source in an aqueous electrolyte. In addition, we utilized oxalic acid as a carbon source, which can be obtained from electrochemical conversion of CO\n                    <jats:sub>2.<\/jats:sub>\n                    Thus, our approach can provide a route for the utilization of anthropogenic CO\n                    <jats:sub>2<\/jats:sub>\n                    and nitrate wastes, which cause serious environmental problems including global warming and eutrophication. Interestingly, the coreduction of oxalic acid and nitrate generated reactive intermediates, which led to C\u2212N bond formation followed by further reduction to an amino acid, namely, glycine. By carefully controlling this multireduction process with a fabricated Cu\u2013Hg electrode, we demonstrated the efficient production of glycine with a faradaic efficiency (F.E.) of up to 43.1\u2009% at \u22121.4\u2005V vs. Ag\/AgCl (current density\u224890\u2005mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ).\n                  <\/jats:p>","DOI":"10.1002\/anie.202108352","type":"journal-article","created":{"date-parts":[[2021,7,29]],"date-time":"2021-07-29T13:34:17Z","timestamp":1627565657000},"page":"21943-21951","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":165,"title":["Electrochemical Synthesis of Glycine from Oxalic Acid and Nitrate"],"prefix":"10.1002","volume":"60","author":[{"given":"Jeong Eun","family":"Kim","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering Seoul National University  Gwanak-ro, Gwanak-gu Seoul 08826 Republic of 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