{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T18:03:18Z","timestamp":1789754598471,"version":"4.0.1"},"reference-count":53,"publisher":"Wiley","issue":"41","license":[{"start":{"date-parts":[[2021,9,1]],"date-time":"2021-09-01T00:00:00Z","timestamp":1630454400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22025504, 21621001, and 21390394"],"award-info":[{"award-number":["22025504, 21621001, and 21390394"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013314","name":"Higher Education Discipline Innovation Project","doi-asserted-by":"publisher","award":["BP0719036 and B17020"],"award-info":[{"award-number":["BP0719036 and B17020"]}],"id":[{"id":"10.13039\/501100013314","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100010031","name":"Postdoctoral Research Foundation of China","doi-asserted-by":"publisher","award":["2020TQ0118 and 2020M681034"],"award-info":[{"award-number":["2020TQ0118 and 2020M681034"]}],"id":[{"id":"10.13039\/501100010031","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2021,10,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>With excellent designability, large accessible inner surface, and high chemical stability, covalent organic frameworks (COFs) are promising candidates as metal\u2010free heterogeneous catalysts. Here, we report two 3D radical\u2010based COFs (JUC\u2010565 and JUC\u2010566) in which radical moieties (TEMPO) are uniformly decorated on the channel walls via a bottom\u2010up approach. Based on grafted functional groups and suitable regular channels, these materials open up the application of COFs as highly efficient and selective metal\u2010free redox catalysts in aerobic oxidation of alcohols to relevant aldehydes or ketones with outstanding turn over frequency (TOF) up to 132\u2005h<jats:sup>\u22121<\/jats:sup>, which has exceeded other TEMPO\u2010modified catalytic materials tested under similar conditions. These stable COF\u2010based catalysts could be easily recovered and reused for multiple runs. This study promotes potential applications of 3D functional COFs anchored with stable radicals in organic synthesis and material science.<\/jats:p>","DOI":"10.1002\/anie.202108357","type":"journal-article","created":{"date-parts":[[2021,8,13]],"date-time":"2021-08-13T10:16:15Z","timestamp":1628849775000},"page":"22230-22235","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":69,"title":["Three\u2010Dimensional Radical Covalent Organic Frameworks as Highly Efficient and Stable Catalysts for Selective Oxidation of Alcohols"],"prefix":"10.1002","volume":"60","author":[{"given":"Fengqian","family":"Chen","sequence":"first","affiliation":[{"name":"State Key Laboratory of Inorganic Synthesis and Preparative Chemistry Jilin University  Changchun 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinyu","family":"Guan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Inorganic Synthesis and Preparative Chemistry Jilin University  Changchun 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Inorganic Synthesis and Preparative Chemistry Jilin University  Changchun 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiehua","family":"Ding","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Inorganic Synthesis and Preparative Chemistry Jilin University  Changchun 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liangkui","family":"Zhu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Inorganic Synthesis and Preparative Chemistry Jilin University  Changchun 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bin","family":"Tang","sequence":"additional","affiliation":[{"name":"Deakin University Institute for Frontier Materials  Geelong Victoria 3216 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Valentin","family":"Valtchev","sequence":"additional","affiliation":[{"name":"Qingdao Institute of Bioenergy and Bioprocess Technology Chinese Academy of Sciences  189 Song Ling Rd Qingdao Shandong 266101 China"},{"name":"Normandie Univ, ENSICAEN UNICAEN CNRS Laboratoire Catalyse et Spectrochimie  6 Marechal Juin 14050 Caen France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yushan","family":"Yan","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Center for Catalytic Science and Technology University of Delaware  Newark DE 19716 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shilun","family":"Qiu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Inorganic Synthesis and Preparative Chemistry Jilin University  Changchun 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3365-5508","authenticated-orcid":false,"given":"Qianrong","family":"Fang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Inorganic Synthesis and Preparative Chemistry Jilin University  Changchun 130012 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,9]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1120411"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1139915"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs35157a"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2CS35072F"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1628"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201705553"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00827F"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00911F"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwz122"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202002038"},{"key":"e_1_2_2_12_1","unstructured":"\u00a0"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja206846p"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4SC00016A"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aac8343"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2352"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-018-0141-5"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b07714"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00033B"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.0c00463"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.enchem.2020.100035"},{"key":"e_1_2_2_22_1","unstructured":"\u00a0"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201310500"},{"key":"e_1_2_2_23_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201310500"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b09563"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b00485"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8DT05056B"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c02225"},{"key":"e_1_2_2_28_1","unstructured":"\u00a0"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-1996-4369"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3gc41459k"},{"key":"e_1_2_2_31_1","unstructured":"\u00a0"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b05001"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.0c02809"},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2020.12.111"},{"key":"e_1_2_2_35_1","unstructured":"\u00a0"},{"key":"e_1_2_2_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201501706"},{"key":"e_1_2_2_36_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201501706"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.6b01711"},{"key":"e_1_2_2_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b02648"},{"key":"e_1_2_2_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b02839"},{"key":"e_1_2_2_40_1","unstructured":"Materials Studio ver.\u20097.0; Accelrys Inc.; San Diego CA."},{"key":"e_1_2_2_41_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767304015442"},{"key":"e_1_2_2_42_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aat7679"},{"key":"e_1_2_2_43_1","unstructured":"\u00a0"},{"key":"e_1_2_2_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202005277"},{"key":"e_1_2_2_44_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202005277"},{"key":"e_1_2_2_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c06485"},{"key":"e_1_2_2_46_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c12499"},{"key":"e_1_2_2_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b09914"},{"key":"e_1_2_2_48_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8TA02664E"},{"key":"e_1_2_2_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201402059"},{"key":"e_1_2_2_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201100047"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202108357","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202108357","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202108357","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,27]],"date-time":"2023-08-27T04:43:29Z","timestamp":1693111409000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202108357"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,9]]},"references-count":53,"journal-issue":{"issue":"41","published-print":{"date-parts":[[2021,10,4]]}},"alternative-id":["10.1002\/anie.202108357"],"URL":"https:\/\/doi.org\/10.1002\/anie.202108357","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,9]]},"assertion":[{"value":"2021-06-23","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2021-09-01","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}