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However, the co\u2010deposition of metal and the narrow range of possible metal nodes limit the scope of this method. In this work, we propose the use of hydrogen peroxide (hydrogen peroxide assisted cathodic deposition or HPACD), to overcome these limitations. Electrochemical measurements indicate that in DMF, hydrogen peroxide is reduced to superoxide anions that deprotonate the carboxylic ligands. This single\u2010electron reduction happens at much higher potentials than all previous reported methods. This prevents the co\u2010deposition of metal and extends the range of possible metal nodes. Various pure MOF films (HKUST\u20101, MIL\u201053(Fe) and MOF\u20105) were prepared via this approach. HPACD was also used for the preparation of patterned MOF films and of flexible Cu\u2010BTC coated paper membranes which reject 99.1\u2009% of Rose Bengal from water with a permeance of 8.4\u2005L\u2009m\n                    <jats:sup>\u22122<\/jats:sup>\n                    \u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009bar\n                    <jats:sup>\u22121<\/jats:sup>\n                    .\n                  <\/jats:p>","DOI":"10.1002\/anie.202108485","type":"journal-article","created":{"date-parts":[[2021,9,20]],"date-time":"2021-09-20T13:28:21Z","timestamp":1632144501000},"page":"24950-24957","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":70,"title":["Cathodic Electrodeposition of MOF Films Using Hydrogen Peroxide"],"prefix":"10.1002","volume":"60","author":[{"given":"Sijie","family":"Xie","sequence":"first","affiliation":[{"name":"Department of Materials Engineering KU Leuven  Kasteelpark Arenberg 44, bus 2450 B-3001 Heverlee Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wouter","family":"Monnens","sequence":"additional","affiliation":[{"name":"Department of Materials Engineering KU Leuven  Kasteelpark Arenberg 44, bus 2450 B-3001 Heverlee Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kai","family":"Wan","sequence":"additional","affiliation":[{"name":"Department of Materials Engineering KU Leuven  Kasteelpark Arenberg 44, bus 2450 B-3001 Heverlee Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Materials Engineering KU Leuven  Kasteelpark Arenberg 44, bus 2450 B-3001 Heverlee Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Guo","sequence":"additional","affiliation":[{"name":"Department of Materials Engineering KU Leuven  Kasteelpark Arenberg 44, bus 2450 B-3001 Heverlee Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"MaoWen","family":"Xu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Luminescent and Real-Time Analytical Chemistry Ministry of Education School of Materials and Energy Southwest University  Chongqing 400715 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ivo F. 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