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Whereas the use of zinc(II) salts gave rise to diamagnetic cages, iron(II) salts yielded metallosupramolecular cages that show spin\u2010crossover behaviour in solution. The spin\u2010transition temperature <jats:italic>T<\/jats:italic><jats:sub>1\/2<\/jats:sub> depends on the incorporated aldehyde component, giving a construction kit for the deliberate synthesis of spin\u2010crossover compounds with tailored transition properties. Incorporation of 4\u2010thiazolecarbaldehyde or <jats:italic>N<\/jats:italic>\u2010methyl\u20102\u2010imidazole\u2010carbaldehyde yielded cages that undergo spin\u2010crossover around room temperature whereas the cage obtained using 1<jats:italic>H<\/jats:italic>\u20104\u2010imidazolecarbaldehyde shows a spin\u2010transition at low temperatures. Three new structures were characterized by synchrotron X\u2010ray diffraction and all structures were characterized by mass spectrometry, NMR and UV\/Vis spectroscopy.<\/jats:p>","DOI":"10.1002\/anie.202108792","type":"journal-article","created":{"date-parts":[[2021,8,12]],"date-time":"2021-08-12T07:21:04Z","timestamp":1628752864000},"page":"22562-22569","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":47,"title":["A Family of Heterobimetallic Cubes Shows Spin\u2010Crossover Behaviour Near Room Temperature"],"prefix":"10.1002","volume":"60","author":[{"given":"Matthias","family":"Hardy","sequence":"first","affiliation":[{"name":"Rheinische Friedrich-Wilhelms-Universit\u00e4t Bonn Kekul\u00e9-Institut f\u00fcr Organische Chemie und Biochemie  Gerhard-Domagk-Str. 1 53121 Bonn Germany"},{"name":"Current address: BASF SE  Speyerer Str. 2 67117 Limburgerhof 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A differential scanning calorimetry (DSC) measurement with[Fe3]also did not lead to insights into the processes upon temperature-changes because the transition is too gradual to cause large enough effects detectable with this technique (SI)."},{"key":"e_1_2_6_122_1","unstructured":"Per uncoupled iron(II) cation in the paramagnetic high-spin state a value of \u03c7MT=3.001\u2005cm3\u2009K\u2009mol\u22121is expected see ref.\u2005[15a]."},{"key":"e_1_2_6_123_1","unstructured":"The calculation of uncertainties is discussed in the SI."}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202108792","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202108792","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202108792","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,27]],"date-time":"2023-08-27T04:39:32Z","timestamp":1693111172000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202108792"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,9,6]]},"references-count":141,"journal-issue":{"issue":"41","published-print":{"date-parts":[[2021,10,4]]}},"alternative-id":["10.1002\/anie.202108792"],"URL":"https:\/\/doi.org\/10.1002\/anie.202108792","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,9,6]]},"assertion":[{"value":"2021-07-02","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2021-09-06","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}