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The mechanistic understanding of propane conversion to aromatics is still challenging due to the complexity of the aromatization process. Herein, by using solid\u2010state NMR spectroscopy and GC\u2010MS, it is shown that cyclopentenyl cations are formed as active intermediates during propane aromatization on Ga\/ZSM\u20105 zeolite. Autocatalysis of propane to aromatics is identified in the induction period. 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