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Introduction of a minor amount of redox\u2010responsive disulfide\u2010functionalized diacrylates (\u226410\u2005wt\u2009%) induced the formation of flower\u2010like shapes. The shape of the particles can be tuned from flower\u2010 to disk\u2010like to spherical by elevating the polymerization temperature. The solvent environment also has a pronounced effect on the particle size. Time\u2010resolved TEM reveals that the final particle morphology was formed in the early stages of the polymerization and that subsequent polymerization resulted in continued particle growth without affecting the morphology. Finally, the degradation of the particles under reducing conditions was much faster for flower\u2010like particles than for spherical particles, likely a result of their higher surface\u2010to\u2010volume ratio.<\/jats:p>","DOI":"10.1002\/anie.202111521","type":"journal-article","created":{"date-parts":[[2021,10,21]],"date-time":"2021-10-21T07:43:18Z","timestamp":1634802198000},"page":"27026-27030","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Flower\u2010Like Colloidal Particles through Precipitation Polymerization of Redox\u2010Responsive Liquid Crystals"],"prefix":"10.1002","volume":"60","author":[{"given":"Xiaohong","family":"Liu","sequence":"first","affiliation":[{"name":"Stimuli-Responsive Functional Materials and Devices Department of Chemical Engineering and Chemistry Eindhoven University of Technology  Groene Loper 3 5612 AE Eindhoven The Netherlands"},{"name":"Institute for Complex Molecular Systems Eindhoven University of Technology  Groene Loper 3 5612 AE Eindhoven The Netherlands"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mohammad\u2010Amin","family":"Moradi","sequence":"additional","affiliation":[{"name":"Institute for Complex Molecular Systems Eindhoven University of Technology  Groene Loper 3 5612 AE Eindhoven The Netherlands"},{"name":"Laboratory of Physical Chemistry Department of Chemical Engineering and Chemistry Eindhoven University of Technology  Groene Loper 3 5612 AE Eindhoven The Netherlands"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tom","family":"Bus","sequence":"additional","affiliation":[{"name":"Stimuli-Responsive Functional Materials and Devices Department of Chemical Engineering and Chemistry Eindhoven University of Technology  Groene Loper 3 5612 AE Eindhoven The Netherlands"},{"name":"Institute for Complex Molecular Systems Eindhoven University of Technology  Groene Loper 3 5612 AE Eindhoven The Netherlands"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michael G.","family":"Debije","sequence":"additional","affiliation":[{"name":"Stimuli-Responsive Functional Materials and Devices Department of Chemical Engineering and Chemistry Eindhoven University of Technology  Groene Loper 3 5612 AE Eindhoven The Netherlands"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Stefan A. 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