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Through co\u2010expression of the OmpF mutant with wild\u2010type P450BM3 in the presence of decoy molecules, the yield of the whole\u2010cell biotransformation of benzene could be considerably improved. Notably, with the decoy molecule C7AM\u2010Pip\u2010Phe the yield duodecupled from 5.7\u2009% to 70\u2009%, with 80\u2009% phenol selectivity. The benzylic hydroxylation of alkyl\u2010 and cycloalkylbenzenes was also examined, and with the aid of decoy molecules, propylbenzene and tetralin were converted to 1\u2010hydroxylated products with 78\u2009% yield and 94\u2009% (R) ee for propylbenzene and 92\u2009% yield and 94\u2009% (S) ee for tetralin. 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