{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T16:34:52Z","timestamp":1791909292097,"version":"4.3.4"},"reference-count":62,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2021,11,25]],"date-time":"2021-11-25T00:00:00Z","timestamp":1637798400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100004663","name":"Ministry of Science and Technology, Taiwan","doi-asserted-by":"publisher","award":["109-2113-M-259-008"],"award-info":[{"award-number":["109-2113-M-259-008"]}],"id":[{"id":"10.13039\/501100004663","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2022,1,10]]},"abstract":"Abstract<\/jats:title>\n \n In sharp contrast to surface hydrides, reactivities of interstitial hydrides are difficult to explore. When treated with a metal ion (Cu\n +<\/jats:sup>\n , Ag\n +<\/jats:sup>\n , and Au\n +<\/jats:sup>\n ), the stable Cu\n I<\/jats:sup>\n dihydride template [Cu\n 11<\/jats:sub>\n H\n 2<\/jats:sub>\n {S\n 2<\/jats:sub>\n P(O\n \n i<\/jats:italic>\n <\/jats:sup>\n Pr)\n 2<\/jats:sub>\n }\n 6<\/jats:sub>\n (C\u2261CPh)\n 3<\/jats:sub>\n ] (\n \n H\n 2<\/jats:sub>\n Cu\n 11<\/jats:sub>\n <\/jats:bold>\n ) generates surprisingly three very different compounds, namely [CuH\n 2<\/jats:sub>\n Cu\n 11<\/jats:sub>\n {S\n 2<\/jats:sub>\n P(O\n \n i<\/jats:italic>\n <\/jats:sup>\n Pr)\n 2<\/jats:sub>\n }\n 6<\/jats:sub>\n (C\u2261CPh)\n 3<\/jats:sub>\n ]\n +<\/jats:sup>\n (\n 1<\/jats:bold>\n ), [AgH\n 2<\/jats:sub>\n Cu\n 14<\/jats:sub>\n {S\n 2<\/jats:sub>\n P(O\n \n i<\/jats:italic>\n <\/jats:sup>\n Pr)\n 2<\/jats:sub>\n }\n 6<\/jats:sub>\n ((C\u2261CPh)\n 6<\/jats:sub>\n ]\n +<\/jats:sup>\n (\n 2<\/jats:bold>\n ), and [AuCu\n 11<\/jats:sub>\n {S\n 2<\/jats:sub>\n P(O\n \n i<\/jats:italic>\n <\/jats:sup>\n Pr)\n 2<\/jats:sub>\n }\n 6<\/jats:sub>\n (C\u2261CPh)\n 3<\/jats:sub>\n Cl] (\n 3<\/jats:bold>\n ). Compounds\n 1<\/jats:bold>\n and\n 2<\/jats:bold>\n are both M\n I<\/jats:sup>\n species and maintain the same number of hydride ligands as their\n \n H\n 2<\/jats:sub>\n Cu\n 11<\/jats:sub>\n <\/jats:bold>\n precursor. Neutron diffraction revealed the first time a trigonal\u2010pyramidal hydride coordination mode in the AgCu\n 3<\/jats:sub>\n environment of\n 2. 3<\/jats:bold>\n has no hydride and exhibits a mixed\u2010valent [AuCu\n 11<\/jats:sub>\n ]\n 10+<\/jats:sup>\n metal core, making it a two\u2010electron superatom.\n <\/jats:p>","DOI":"10.1002\/anie.202113266","type":"journal-article","created":{"date-parts":[[2021,11,9]],"date-time":"2021-11-09T22:25:07Z","timestamp":1636496707000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":40,"title":["Reactivities of Interstitial Hydrides in a Cu\n 11<\/sub>\n Template: En Route to Bimetallic Clusters"],"prefix":"10.1002","volume":"61","author":[{"given":"Rhone P. Brocha","family":"Silalahi","sequence":"first","affiliation":[{"name":"Department of Chemistry National Dong Hwa University No. 1, Sec 2, Da Hsueh Rd. Hualien 974301 Taiwan, R.O.C."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qi","family":"Wang","sequence":"additional","affiliation":[{"name":"Univ Rennes CNRS, ISCR-UMR 6226 35000 Rennes France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian\u2010Hong","family":"Liao","sequence":"additional","affiliation":[{"name":"Department of Chemistry National Dong Hwa University No. 1, Sec 2, Da Hsueh Rd. Hualien 974301 Taiwan, R.O.C."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tzu\u2010Hao","family":"Chiu","sequence":"additional","affiliation":[{"name":"Department of Chemistry National Dong Hwa University No. 1, Sec 2, Da Hsueh Rd. Hualien 974301 Taiwan, R.O.C."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying\u2010Yann","family":"Wu","sequence":"additional","affiliation":[{"name":"Institute of Chemistry Academia Sinica Taipei 11528 Taiwan, R.O.C."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoping","family":"Wang","sequence":"additional","affiliation":[{"name":"Neutron Scattering Division Neutron Sciences Directorate Oak Ridge National Laboratory Oak Ridge TN 37831 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Samia","family":"Kahlal","sequence":"additional","affiliation":[{"name":"Univ Rennes CNRS, ISCR-UMR 6226 35000 Rennes France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4469-7922","authenticated-orcid":false,"given":"Jean\u2010Yves","family":"Saillard","sequence":"additional","affiliation":[{"name":"Univ Rennes CNRS, ISCR-UMR 6226 35000 Rennes France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0801-6499","authenticated-orcid":false,"given":"C. 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