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A variety of aryl, 1\u00b0, 2\u00b0, 3\u00b0\u2010alkyl 2\u2010pyridyl esters can act as acyl electrophiles while\n                    <jats:italic>N<\/jats:italic>\n                    \u2010(acyloxy)phthalimides (NHPI esters) act as 1\u00b0, 2\u00b0, 3\u00b0\u2010radical precursors. Our PARAC strategy provides an alternative and reliable way to synthesize various sterically congested 3\u00b0\u20103\u00b0, 3\u00b0\u20102\u00b0, and aryl\u20103\u00b0 ketones under mild and highly unified conditions, which have been otherwise difficult to access. The combined experimental and computational studies identified a Ni\n                    <jats:sup>0<\/jats:sup>\n                    \/Ni\n                    <jats:sup>I<\/jats:sup>\n                    \/Ni\n                    <jats:sup>III<\/jats:sup>\n                    pathway for ketone formation.\n                  <\/jats:p>","DOI":"10.1002\/anie.202114731","type":"journal-article","created":{"date-parts":[[2021,11,15]],"date-time":"2021-11-15T23:34:20Z","timestamp":1637019260000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":68,"title":["From Esters to Ketones via a Photoredox\u2010Assisted Reductive Acyl Cross\u2010Coupling Strategy"],"prefix":"10.1002","volume":"61","author":[{"given":"Xiaoxiang","family":"Xi","sequence":"first","affiliation":[{"name":"Key Laboratory of Material Chemistry for Energy Conversion and Storage Ministry of Education Hubei Key Laboratory of Bioinorganic Chemistry and Materia Medica School of Chemistry and Chemical Engineering Huazhong University of Science and Technology (HUST)  1037 Luoyu Road Wuhan 430074 P. 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