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In this study, SnF\n                    <jats:sub>2<\/jats:sub>\n                    was demonstrated not only to be an efficient catalyst for the polymerization of DOL at room temperature, but also an effective additive for improving interfacial wettability and suppressing dendrite through the reaction with Li\u2010metal and the formation of LiF\/Li\n                    <jats:sub>\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    Sn based composite solid electrolyte interlayer(SEI). Using the SnF\n                    <jats:sub>2<\/jats:sub>\n                    polymerized P\u2010DOL containing 1\u2005M LiTFSI as SPE(P\u2010DOL\u2010SPE), obviously denser Li\u2010deposition was obtained, and the all\u2010solid\u2010state(ASS) Li\/LiFePO\n                    <jats:sub>4<\/jats:sub>\n                    cell delivered stable cycling over 350 cycles at 45\u2009\u00b0C. At the same time, the irreversible decomposition of P\u2010DOL\u2010SPE into formaldehyde and small molecule epoxides are observed at 110\u2009\u00b0C, which is even initiated at lower temperature of 40\u2009\u00b0C under vacuum. This thermal decomposition of P\u2010DOL\u2010SPE in pouch cell causes huge volume swell, and therefore putting a strict limitation on the operating temperature window for the P\u2010DOL based electrolytes.\n                  <\/jats:p>","DOI":"10.1002\/anie.202114805","type":"journal-article","created":{"date-parts":[[2021,11,30]],"date-time":"2021-11-30T13:12:12Z","timestamp":1638277932000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":108,"title":["SnF\n                    <sub>2<\/sub>\n                    \u2010Catalyzed Formation of Polymerized Dioxolane as Solid Electrolyte and its Thermal Decomposition Behavior"],"prefix":"10.1002","volume":"61","author":[{"given":"Wei","family":"Li","sequence":"first","affiliation":[{"name":"Beijing Advanced Innovation Center for Soft Matter Science and Engineering State Key Laboratory of Organic-Inorganic Composites Beijing University of Chemical Technology  Beijing 100029 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