{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,3]],"date-time":"2026-06-03T17:22:01Z","timestamp":1780507321050,"version":"3.54.1"},"reference-count":93,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2021,12,23]],"date-time":"2021-12-23T00:00:00Z","timestamp":1640217600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100004731","name":"Natural Science Foundation of Zhejiang Province","doi-asserted-by":"publisher","award":["R21B040004"],"award-info":[{"award-number":["R21B040004"]}],"id":[{"id":"10.13039\/501100004731","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["51973186"],"award-info":[{"award-number":["51973186"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["91956123"],"award-info":[{"award-number":["91956123"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22101253"],"award-info":[{"award-number":["22101253"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2022,2,7]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Construction of well\u2010defined sulfur\u2010rich macromolecules in a facile manner is an interesting but challenging topic. Herein, we disclose how to readily construct well\u2010defined triblock sulfur\u2010rich thermoplastic elastomers via a self\u2010switchable isothiocyanate\/episulfide copolymerization and air\u2010assisted oxidative coupling strategy. During self\u2010switchable polymerization, alternating copolymerization of isothiocyanate and episulfide occurs initially due to the lower energy barrier for isothiocyanate insertion with respect to successive episulfide ring\u2010opening. After exhaustion of isothiocyanate, ring\u2010opening polymerization of episulfide begins, providing diblock polymers. Subsequent exposure of the reaction to air leads to a transformation of diblock copolymers into triblock thermoplastic elastomers. This protocol can be extended to diverse isothiocyanates and episulfides, allowing fine\u2010tuning of the performance of the produced sulfur\u2010rich thermoplastic elastomers.<\/jats:p>","DOI":"10.1002\/anie.202115189","type":"journal-article","created":{"date-parts":[[2021,12,6]],"date-time":"2021-12-06T03:00:04Z","timestamp":1638759604000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":38,"title":["One\u2010Pot Construction of Sulfur\u2010Rich Thermoplastic Elastomers Enabled by Metal\u2010Free Self\u2010Switchable Catalysis and Air\u2010Assisted Coupling"],"prefix":"10.1002","volume":"61","author":[{"given":"Xiao\u2010Feng","family":"Zhu","sequence":"first","affiliation":[{"name":"MOE Key Laboratory of Macromolecular Synthesis and Functionalization Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province Department of Polymer Science and Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guan\u2010Wen","family":"Yang","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Macromolecular Synthesis and Functionalization Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province Department of Polymer Science and Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rui","family":"Xie","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Macromolecular Synthesis and Functionalization Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province Department of Polymer Science and Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8935-964X","authenticated-orcid":false,"given":"Guang\u2010Peng","family":"Wu","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Macromolecular Synthesis and Functionalization Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province Department of Polymer Science and Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,12,23]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2020.101342"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2019.04.002"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00161H"},{"key":"e_1_2_7_5_1","unstructured":"\u00a0"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1314"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2011.11.001"},{"key":"e_1_2_7_8_1","unstructured":"\u00a0"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.6b00211"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma201063t"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.0c01068"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF01493208"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.22611"},{"key":"e_1_2_7_14_1","unstructured":"\u00a0"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja1056938"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja062695v"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1097-4628(19960711)61:2<333::AID-APP16>3.0.CO;2-4"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1080\/10601327308060508"},{"key":"e_1_2_7_19_1","unstructured":"\u00a0"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma2026385"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200801415"},{"key":"e_1_2_7_21_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200801415"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.7b02042"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.7b01905"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b01295"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.0c07283"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.0c02647"},{"key":"e_1_2_7_27_2","doi-asserted-by":"publisher","DOI":"10.3762\/bjoc.10.187"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma102238u"},{"key":"e_1_2_7_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.9b00439"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-10481-w"},{"key":"e_1_2_7_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.8b00865"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201810083"},{"key":"e_1_2_7_32_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201810083"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9PY01508F"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/marc.202000436"},{"key":"e_1_2_7_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201914216"},{"key":"e_1_2_7_35_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201914216"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201801400"},{"key":"e_1_2_7_36_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201801400"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.9b00001"},{"key":"e_1_2_7_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b04541"},{"key":"e_1_2_7_39_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202015339"},{"key":"e_1_2_7_39_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202015339"},{"key":"e_1_2_7_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c00382"},{"key":"e_1_2_7_41_1","unstructured":"\u00a0"},{"key":"e_1_2_7_42_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2021.101397"},{"key":"e_1_2_7_43_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c03250"},{"key":"e_1_2_7_44_1","unstructured":"\u00a0"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.trechm.2020.05.002"},{"key":"e_1_2_7_46_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7QI00013H"},{"key":"e_1_2_7_47_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.7b02690"},{"key":"e_1_2_7_48_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.9b01777"},{"key":"e_1_2_7_49_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201303703"},{"key":"e_1_2_7_50_2","first-page":"467","volume":"52","author":"Zhang Y.-Y.","year":"2021","journal-title":"Acta Polym. Sin."},{"key":"e_1_2_7_51_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.8b00576"},{"key":"e_1_2_7_52_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.7b02715"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/0014-3057(70)90116-3"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma9900434"},{"key":"e_1_2_7_55_1","unstructured":"\u00a0"},{"key":"e_1_2_7_56_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.0c00711"},{"key":"e_1_2_7_57_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.0c00687"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.0c00831"},{"key":"e_1_2_7_59_1","unstructured":"\u00a0"},{"key":"e_1_2_7_60_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c00243"},{"key":"e_1_2_7_61_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.9b00948"},{"key":"e_1_2_7_62_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-17474-0"},{"key":"e_1_2_7_63_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201409468"},{"key":"e_1_2_7_63_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201409468"},{"key":"e_1_2_7_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b11066"},{"key":"e_1_2_7_65_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201812135"},{"key":"e_1_2_7_65_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201905235"},{"key":"e_1_2_7_66_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2016.09.003"},{"key":"e_1_2_7_67_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00345"},{"key":"e_1_2_7_68_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202012565"},{"key":"e_1_2_7_68_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202012565"},{"key":"e_1_2_7_69_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201805200"},{"key":"e_1_2_7_69_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201805200"},{"key":"e_1_2_7_70_1","unstructured":"\u00a0"},{"key":"e_1_2_7_71_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.6b02089"},{"key":"e_1_2_7_72_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.1c00770"},{"key":"e_1_2_7_73_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.8b01961"},{"key":"e_1_2_7_74_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.8b00404"},{"key":"e_1_2_7_75_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar500121d"},{"key":"e_1_2_7_76_2","doi-asserted-by":"publisher","DOI":"10.1021\/mz500339h"},{"key":"e_1_2_7_77_2","doi-asserted-by":"publisher","DOI":"10.1021\/bm700699g"},{"key":"e_1_2_7_78_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b13106"},{"key":"e_1_2_7_79_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.8b00143"},{"key":"e_1_2_7_80_1","unstructured":"\u00a0"},{"key":"e_1_2_7_81_2","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.8b05084"},{"key":"e_1_2_7_82_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9PY01085H"},{"key":"e_1_2_7_83_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c03651"},{"key":"e_1_2_7_84_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202007417"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202115189","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202115189","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202115189","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,27]],"date-time":"2023-08-27T08:58:26Z","timestamp":1693126706000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202115189"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,12,23]]},"references-count":93,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2022,2,7]]}},"alternative-id":["10.1002\/anie.202115189"],"URL":"https:\/\/doi.org\/10.1002\/anie.202115189","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,12,23]]},"assertion":[{"value":"2021-11-09","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2021-12-23","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202115189"}}