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Among them, copper halide hybrid molecular compounds with discrete inorganic modules are particularly interesting due to their high quantum efficiency. However, synthesizing highly efficient blue\u2010emitting molecular clusters remains challenging. Here, we report a novel and facile strategy for the design and synthesis of highly luminescent copper halide hybrid structures by fabricating coordinated anionic inorganic modules in these ionic species. By using this approach, a family of strongly blue\u2010emitting copper halide hybrid ionic structures has been prepared with high internal quantum yields up to 98\u2009%. Strong luminescence from the combination of ionic and covalent bonds in these compounds make them ideal candidates as alternative, rare\u2010earth\u2010element free light\u2010emitting materials for possible use in optoelectronic devices.<\/jats:p>","DOI":"10.1002\/anie.202115225","type":"journal-article","created":{"date-parts":[[2021,12,3]],"date-time":"2021-12-03T01:06:56Z","timestamp":1638493616000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":83,"title":["Coordinated Anionic Inorganic Module\u2014An Efficient Approach Towards Highly Efficient Blue\u2010Emitting Copper Halide Ionic Hybrid Structures"],"prefix":"10.1002","volume":"61","author":[{"given":"Haibo","family":"Li","sequence":"first","affiliation":[{"name":"School of Chemical Engineering and Technology Sun Yat-sen University  Zhuhai 519082, Guangdong P. R. 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