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Compared with other solid supramolecules P\u2212R\/CB[7] (R=\u2212CN, \u2212CO<jats:sub>2<\/jats:sub>Et, \u2212Me), P\u2212CF<jats:sub>3<\/jats:sub>\/CB[7] displays the longest lifetime (2.2\u2005s), which is probably attributed to the fluorophilic interaction of cucurbiturils leading to a uncommon host\u2013guest interaction between 4\u2010phenylpyridium with \u2212CF<jats:sub>3<\/jats:sub> and CB[7]. Furthermore, the RTP solid supramolecular assembly (donors) can further react with organic dyes Eosin Y or SR101 (acceptors) to form ternary supramolecular systems featuring ultralong phosphorescence energy transfer (PpET) and visible delayed fluorescence (yellow for EY at 568\u2005nm and red for SR101 at 620\u2005nm). Significantly, the ultralong multicolor PpET supramolecular assembly can be further applied in fields of anti\u2010counterfeiting and information encryption and painting.<\/jats:p>","DOI":"10.1002\/anie.202115265","type":"journal-article","created":{"date-parts":[[2021,12,7]],"date-time":"2021-12-07T16:16:47Z","timestamp":1638893807000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":92,"title":["Tunable Second\u2010Level Room\u2010Temperature Phosphorescence of Solid Supramolecules between Acrylamide\u2013Phenylpyridium Copolymers and Cucurbit[7]uril"],"prefix":"10.1002","volume":"61","author":[{"given":"Wen\u2010Wen","family":"Xu","sequence":"first","affiliation":[{"name":"College of Chemistry State Key Laboratory of Elemento-Organic Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yong","family":"Chen","sequence":"additional","affiliation":[{"name":"College 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