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In these chemodivergent reactions, cooperatively catalyzed by a Ir\n                    <jats:sup>I<\/jats:sup>\n                    \/(phosphoramidite,olefin) complex and Sc(OTf)\n                    <jats:sub>3<\/jats:sub>\n                    , vinyl azides act as the surrogate for both amide enolates and ketone enolates. The desiccant (molecular sieves) plays a crucial role in controlling the chemodivergency of this enantioconvergent and regioselective reaction: Under otherwise identical reaction conditions, the presence of the desiccant led to \u03b1\u2010allenylic amides, while its absence resulted in \u03b1\u2010allenylic ketones. Utilizing racemic allenylic alcohols as the alkylating agent, the overall process represents a dynamic kinetic asymmetric transformation (DyKAT), where both the products are formed with the same absolute configuration. To the best of our knowledge, this is the first example of the use of vinyl azide as the ketone enolate surrogate in an enantioselective transformation.\n                  <\/jats:p>","DOI":"10.1002\/anie.202115821","type":"journal-article","created":{"date-parts":[[2022,1,19]],"date-time":"2022-01-19T09:38:24Z","timestamp":1642585104000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":49,"title":["Iridium\u2010Catalyzed Enantioselective and Chemodivergent Allenylic Alkylation of Vinyl Azides for the Synthesis of \u03b1\u2010Allenylic Amides and Ketones**"],"prefix":"10.1002","volume":"61","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3470-069X","authenticated-orcid":false,"given":"Aditya","family":"Chakrabarty","sequence":"first","affiliation":[{"name":"Department of Organic Chemistry Indian Institute of Science Bangalore 560 012 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9651-6228","authenticated-orcid":false,"given":"Santanu","family":"Mukherjee","sequence":"additional","affiliation":[{"name":"Department of Organic Chemistry Indian Institute of Science Bangalore 560 012 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,2]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201913645"},{"key":"e_1_2_7_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201913645"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b11790"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00475"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00284"},{"key":"e_1_2_7_6_1","unstructured":"For selected reviews see:"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar500167f"},{"key":"e_1_2_7_8_2","first-page":"967","volume-title":"Organotransition Metal Chemistry","author":"Hartwig J. 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