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Here, we describe the isolation and full characterization of the first tetraamido tin(II) dianion, its behavior as ligand towards transition metals, and its reactivity as a tin\u2010centered nucleophile. Experimental values such as the Tolman electronic parameter (TEP) and computations attest tin\u2010located \u03c3\u2010donor ability exceeding that of carbenes or electron\u2010rich phosphines. Against transition metals, the stannate(II) can act as <jats:italic>\u03b7<\/jats:italic><jats:sup>1<\/jats:sup>\u2010 or <jats:italic>\u03b7<\/jats:italic><jats:sup>5<\/jats:sup>\u2010type ligand. With aldehydes, it reacts by hydride substitution to give valuable acyl stannates. The reductive dehalogenation of iodobenzene indicates facile redox pathways mediated by halogen bond interaction. Calix[4]pyrrolato stannate(II) represents the first example of this macrocyclic ligand in low\u2010valent <jats:italic>p<\/jats:italic>\u2010block element chemistry.<\/jats:p>","DOI":"10.1002\/anie.202116615","type":"journal-article","created":{"date-parts":[[2022,1,12]],"date-time":"2022-01-12T11:33:40Z","timestamp":1641987220000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["Calix[4]pyrrolato Stannate(II): A Tetraamido Tin(II) Dianion and Strong Metal\u2010Centered \u03c3\u2010Donor"],"prefix":"10.1002","volume":"61","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9363-7697","authenticated-orcid":false,"given":"Heiko","family":"Ruppert","sequence":"first","affiliation":[{"name":"Anorganisch-Chemisches Institut Ruprecht-Karls-Universit\u00e4t Heidelberg  Im Neuenheimer Feld 270 69120 Heidelberg 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