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The reactive catalytic species are generated from La grafted at the Br\u00f8nsted acid sites (BAS) in micropores of the zeolite, whereas silanoate\u2010 and aluminoate\u2010grafted sites are inactive under the reaction conditions. During typical catalytic borylations, conversion to phenyl pinacolborane (PhBpin) is zero\u2010order in HBpin concentration. A turnover number (TON) of 167 is accessed by capping external silanols, selectively grafting at BAS sites, and adding HBpin slowly to the reaction.<\/jats:p>","DOI":"10.1002\/anie.202117394","type":"journal-article","created":{"date-parts":[[2022,2,1]],"date-time":"2022-02-01T15:11:40Z","timestamp":1643728300000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Supported Lanthanum Borohydride Catalyzes CH Borylation Inside Zeolite Micropores"],"prefix":"10.1002","volume":"61","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2236-6612","authenticated-orcid":false,"given":"Yuting","family":"Li","sequence":"first","affiliation":[{"name":"U.S. DOE Ames Laboratory Iowa State University  Ames IA 50011 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